Spectroscopy Unknown. The spectra and data provided were obtained from a pure organic molecule. For ¹H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants (J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a "zoom-in" on an important part of the spectrum. Mass Spectrum (not shown): [M] = 254 (100 %) m/z IR Spectrum (not shown): 3060, 2981, 1745, 1600, 1495 cm¹ (all listed are strong (s) unless otherwise indicated) ¹H NMR Spectrum (400 MHz, CDCI3, 25 °C)

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....
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identify the unkown using fhe C NMR and H NMR spectrums.
Spectroscopy Unknown. The spectra and data provided were obtained from a pure organic molecule.
For ¹H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants.
(J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a
"zoom-in" on an important part of the spectrum.
Mass Spectrum (not shown): [M] = 254 (100 %) m/z
IR Spectrum (not shown): 3060, 2981, 1745, 1600, 1495 cm³¹ (all listed are strong (s) unless otherwise indicated)
¹H NMR Spectrum (400 MHz, CDCI3, 25 °C)
8
10H
m
(C)
180
160
13C NMR Spectrum, proton-decoupled (125 MHz, CDCI 3, 25 °C)
(C)
5
d
140
2H 1H
(CH) (CH)
(CH)
PPM
120
100
PPM
80
(CH₂)
q
2H
60
3H
(CH) (CH₂) (CH3)
8
20
o
Transcribed Image Text:Spectroscopy Unknown. The spectra and data provided were obtained from a pure organic molecule. For ¹H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants. (J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a "zoom-in" on an important part of the spectrum. Mass Spectrum (not shown): [M] = 254 (100 %) m/z IR Spectrum (not shown): 3060, 2981, 1745, 1600, 1495 cm³¹ (all listed are strong (s) unless otherwise indicated) ¹H NMR Spectrum (400 MHz, CDCI3, 25 °C) 8 10H m (C) 180 160 13C NMR Spectrum, proton-decoupled (125 MHz, CDCI 3, 25 °C) (C) 5 d 140 2H 1H (CH) (CH) (CH) PPM 120 100 PPM 80 (CH₂) q 2H 60 3H (CH) (CH₂) (CH3) 8 20 o
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