Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 O3(g) → O₂(g) + O(g) k₁ 2 03(g) + O(g) → 20₂(g) k₂ Suppose also k₁k₂. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: 0 Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k₁, K2, and (if necessary) the rate and I for constante l rate = k k0 k = 0- C C
Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 O3(g) → O₂(g) + O(g) k₁ 2 03(g) + O(g) → 20₂(g) k₂ Suppose also k₁k₂. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: 0 Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k₁, K2, and (if necessary) the rate and I for constante l rate = k k0 k = 0- C C
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 66AP
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Suppose the decomposition of ozone proceeds by the following mechanism:
step elementary reaction rate constant
(g) (g) (g)
(g) (g) (g)
Suppose also ≫. That is, the first step is much faster than the second.
Write the balanced chemical equation for the overall chemical reaction :
Write the experimentally-observable rate law for the overall chemical reaction.
Note: your answer should not contain the concentrations of any intermediates.
Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k-1 and k-2 for the reverse of the two elementary reactions in the mechanism.
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