Table D.2 Dissociation Constants for Bases at 25 °C Name Kb Ammonia 1.8 x 10-5 Methylamine Ethylamine Dimethylamine Trimethylamine Formula NH, CH3NH₂ C,HẠNH, (CH;),NH (CH3)3N 4.4 X 104 6.4 X 104 5.4 X 104 6.4 x 10-5 Which of the following are true from the table of base dissociation constants? Select the correct response(s): Electron-donating groups make the lone pair of nitrogen more available for donation. Steric factors do not affect the basicity of the amine. The more electron-donating groups the more basic is the amine. Electron-donating groups make the lone pair of nitrogen less available for donation.. The availability of the lone pair of nitrogen is decreased by steric factors. The smaller the Kb the more available the lone pair of nitrogen. The larger the Kb the more available the lone pair of nitrogen.

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section: Chapter Questions
Problem 118IL: Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H)...
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Table D.2 Dissociation Constants for Bases at 25 °C
Name
Kb
Ammonia
1.8 x 10-5
Methylamine
Ethylamine
Dimethylamine
Trimethylamine
Formula
NH3
CH3NH₂
C,HẠNH,
(CH;),NH
(CH3)3N
4.4 x 104
6.4 X 104
5.4 X 104
6.4 x 10-5
Which of the following are true from the table of base
dissociation constants?
Select the correct response(s):
Electron-donating groups make the lone
pair of nitrogen more available for donation.
Steric factors do not affect the basicity of
the amine.
The more electron-donating groups the
more basic is the amine.
Electron-donating groups make the lone
pair of nitrogen less available for donation..
The availability of the lone pair of nitrogen
is decreased by steric factors.
The smaller the Kb the more available the
lone pair of nitrogen.
The larger the Kb the more available the
lone pair of nitrogen.
Transcribed Image Text:Table D.2 Dissociation Constants for Bases at 25 °C Name Kb Ammonia 1.8 x 10-5 Methylamine Ethylamine Dimethylamine Trimethylamine Formula NH3 CH3NH₂ C,HẠNH, (CH;),NH (CH3)3N 4.4 x 104 6.4 X 104 5.4 X 104 6.4 x 10-5 Which of the following are true from the table of base dissociation constants? Select the correct response(s): Electron-donating groups make the lone pair of nitrogen more available for donation. Steric factors do not affect the basicity of the amine. The more electron-donating groups the more basic is the amine. Electron-donating groups make the lone pair of nitrogen less available for donation.. The availability of the lone pair of nitrogen is decreased by steric factors. The smaller the Kb the more available the lone pair of nitrogen. The larger the Kb the more available the lone pair of nitrogen.
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