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The below synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. Reagents HCI HBr compound a compound b a. b. C. d. e. f. g. h. i. j. k. 1. H₂O, H₂SO4 Br₂ Cl₂ H₂, Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 Pd Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O₂, NaOH O3 then (CH3)2S 2 equivalents of NaNH₂ H₂, Lindlar's catalyst m. n. O. Na/NH3 p. H₂SO4, HgSO4 q. r. (sia)2BH then H₂O₂, NaOH 1 equivalent of NaNH₂

The below synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. Reagents HCI HBr compound a compound b a. b. C. d. e. f. g. h. i. j. k. 1. H₂O, H₂SO4 Br₂ Cl₂ H₂, Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 Pd Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O₂, NaOH O3 then (CH3)2S 2 equivalents of NaNH₂ H₂, Lindlar's catalyst m. n. O. Na/NH3 p. H₂SO4, HgSO4 q. r. (sia)2BH then H₂O₂, NaOH 1 equivalent of NaNH₂

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The below synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. Reagents a. HCI b. HBr c. H₂O, H₂SO4 d. compound a | ● compound b e. f. g. h. i. j. ? Br₂ Cl₂ H₂, Pd Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 k. I. Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O₂, NaOH O3 then (CH3)2S In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. m. n. O. p. q. r. Sn [F 2 equivalents of NaNH2 H₂, Lindlar's catalyst • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu. Na/NH3 H₂SO4, HgSO4 (sia)₂BH then H₂O₂, NaOH 1 equivalent of NaNH₂
Transcribed Image Text:The below synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. Reagents a. HCI b. HBr c. H₂O, H₂SO4 d. compound a | ● compound b e. f. g. h. i. j. ? Br₂ Cl₂ H₂, Pd Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 k. I. Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O₂, NaOH O3 then (CH3)2S In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. m. n. O. p. q. r. Sn [F 2 equivalents of NaNH2 H₂, Lindlar's catalyst • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu. Na/NH3 H₂SO4, HgSO4 (sia)₂BH then H₂O₂, NaOH 1 equivalent of NaNH₂
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