The gas phase decomposition of hydrogen peroxide at 400 °C H₂O₂(g) → H₂O(g) + O₂(g) is second order in H₂O₂ with a rate constant of 0.650 1 M-s If the initial concentration of H₂O₂ is 0.221 M, the concentration of H₂O₂ will be M after 21.5 seconds have passed.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.5: Temperature And Reaction Rate: The Arrhenius Equation
Problem 11.9E: The frequency factor A is 6.31 108 L mol1 s1 and the activation energy is 10. kJ/mol for the...
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The gas phase decomposition of hydrogen peroxide at 400 °C
H₂O₂(g) → H₂O(g) + ½/2O₂(g)
is second order in
H₂O₂ with a rate constant of 0.650
1
M-s
If the initial concentration of
H₂O₂ is 0.221 M, the concentration of
H₂O₂ will be
M after 21.5 seconds have passed.
Transcribed Image Text:The gas phase decomposition of hydrogen peroxide at 400 °C H₂O₂(g) → H₂O(g) + ½/2O₂(g) is second order in H₂O₂ with a rate constant of 0.650 1 M-s If the initial concentration of H₂O₂ is 0.221 M, the concentration of H₂O₂ will be M after 21.5 seconds have passed.
Determine half-life, order, and k from concentration-time data.
The following data were collected for the gas phase decomposition of sulfuryl chloride at 600 K.
SO₂Cl₂(g) SO₂(g) + Cl₂(g)
[SO₂Cl₂], M 4.43x10-3
time, min 0
2.22x10-3 1.11x10-3
186.00
372.00
5.55x10-4
558.00
(a) What is the half-life for the reaction when [SO₂Cl₂] = 4.43x10-3 M?
(b) What is the half-life for the reaction when [SO₂Cl₂] = 2.22x10-³ M?
(c) Is the reaction first order?
If so, what is the rate constant for the reaction? (If not first order leave blank).
min
min
min ¹
Transcribed Image Text:Determine half-life, order, and k from concentration-time data. The following data were collected for the gas phase decomposition of sulfuryl chloride at 600 K. SO₂Cl₂(g) SO₂(g) + Cl₂(g) [SO₂Cl₂], M 4.43x10-3 time, min 0 2.22x10-3 1.11x10-3 186.00 372.00 5.55x10-4 558.00 (a) What is the half-life for the reaction when [SO₂Cl₂] = 4.43x10-3 M? (b) What is the half-life for the reaction when [SO₂Cl₂] = 2.22x10-³ M? (c) Is the reaction first order? If so, what is the rate constant for the reaction? (If not first order leave blank). min min min ¹
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