The leaves of the Brazilian Tree Senna multijunga contain a number of pryidine alkaloids that inhibit acetylcholinterinase. Two recentyl isolated isomeric compounds have the strcture have the strcture shown below. (NOTE: M=293) Use the mass spectral data provided to determine the precise location of the hydroxyl group in each isomer.  Isomer A: EI-MS, m/z(rel. int): 222(20), 150(10), 136(25), 123(100) Isomer B:EI-MS, m/z(re;. int): 236(20), 150(10), 136(25), 123(100)

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter9: Aqueous Solutions And Chemical Equilibria
Section: Chapter Questions
Problem 9.20QAP
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The leaves of the Brazilian Tree Senna multijunga contain a number of pryidine alkaloids that inhibit acetylcholinterinase. Two recentyl isolated isomeric compounds have the strcture have the strcture shown below. (NOTE: M=293) Use the mass spectral data provided to determine the precise location of the hydroxyl group in each isomer. 

Isomer A: EI-MS, m/z(rel. int): 222(20), 150(10), 136(25), 123(100)

Isomer B:EI-MS, m/z(re;. int): 236(20), 150(10), 136(25), 123(100)

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