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the limiting reactant to determine ΔH = qrxn/mol of limiting
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- Graphite is burned in oxygen to give carbon monoxide and carbon dioxide. If the product mixture is 33% CO and 67% CO2 by mass, what is the heat from the combustion of 1.00 g of graphite?Carbon dioxide from the atmosphere weathers, or dissolves, limestone (CaCO3) by the reaction CaCO3(s)+CO2(g)+H2O(l)Ca2(aq)+2HCO3(aq) Obtain H for this reaction. See Table 6.2 for the data.Insoluble AgCl(s) precipitates when solutions of AgNO3(aq) and NaCl(aq) are mixed. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) rH = ? To measure the energy evolved in this reaction, 250. mL of 0.16 M AgNO3(aq) and 125 mL of 0.32 M NaCl(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises from 21.15 C to 22.90 C. Calculate the enthalpy change for the precipitation of AgCl(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL and its specific heat capacity is 4.2 J/g K.)
- A lead ore, galena, consisting mainly of lead(II) sulfide, is the principal source of lead. To obtain the lead, the ore is first heated in the air to form lead oxide. PbS(s)+32 O2(g)PbO(s)+SO2(g)H=415.4kJ The oxide is then reduced to metal with carbon. PbO(s)+C(s)Pb(s)+CO(g)H=+108.5kJCalculate H for the reaction of one mole of lead(II) sulfide with oxygen and carbon, forming lead, sulfur dioxide, and carbon monoxide.9.58 For the reaction C2H2(g)+2H2(g)C2H6,H=136 kJ. What are the ratios that can be defined between moles of substances and energy?How much heat is released when a mixture containing 10.0 g NH3 and 20.0 g O2 reacts by the following equation? 4NH3(g)+5O2(g)4NO(g)+6H2O(g);H=906kJ
- The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.9.89 A sample of gas is 80.0% CH4 and 20.0% C2H6 by mass. What is the heat from the combustion of 1.00 g of this mixture? Assume the products are CO2 (g) and H2O (l).
- How much heat is released when a mixture containing 10.0 g CS2 and 10.0 g Cl2 reacts by the following equation? CS2(g)+3Cl2(g)S2Cl2(g)+CCl4(g);H=230kJA _________ is a device used to determine the heat associated with a chemical reaction.Chlorine dioxide, ClO2, is a reddish yellow gas used in bleaching paper pulp. The average speed of a ClO2 molecule at 25C is 306 m/s. What is the kinetic energy (in joules) of a ClO2 molecule moving at this speed?
