The total concentration of Ca²+ and Mg²+ in a sample of hard water was determined by titrating a 0.100-L sample of the water with a solution of EDTA. The EDTA chelates the two cations: Mg+ + [EDTA]+ Ca2+ + [EDTA]+ [Mg(EDTA)]²- [Ca(EDTA)]?- It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach the end point in the titration. A second 0.100-L sample was then treated with sulfate ion to precipitate Ca?+ as calcium sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104 M [EDTA]*. Calculate the concentrations of Mg²+ and Ca2 in the hard water in mg/L.

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Chapter1: Chemical Foundations
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The total concentration of Ca²+ and Mg²+ in a sample of
hard water was determined by titrating a 0.100-L sample of
the water with a solution of EDTA. The EDTA chelates
the two cations:
Mg+ + [EDTA]+
Ca2+ + [EDTA]+
[Mg(EDTA)]²-
[Ca(EDTA)]?-
It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach
the end point in the titration. A second 0.100-L sample was
then treated with sulfate ion to precipitate Ca?+ as calcium
sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104
M [EDTA]*. Calculate the concentrations of Mg²+ and
Ca2 in the hard water in mg/L.
Transcribed Image Text:The total concentration of Ca²+ and Mg²+ in a sample of hard water was determined by titrating a 0.100-L sample of the water with a solution of EDTA. The EDTA chelates the two cations: Mg+ + [EDTA]+ Ca2+ + [EDTA]+ [Mg(EDTA)]²- [Ca(EDTA)]?- It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach the end point in the titration. A second 0.100-L sample was then treated with sulfate ion to precipitate Ca?+ as calcium sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104 M [EDTA]*. Calculate the concentrations of Mg²+ and Ca2 in the hard water in mg/L.
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