Two samples with narrow molecular weight distributions are prepared of a new polymer. Some measurements are made in acetone and in hexane. sample A in acetone have Mn (osmotic pressure) 85000 Sample A Acetone, 25°C Parameter Second viral coeff. Intrinsic viscosity Intrinsic viscosity 0 0.87 dl/g 1.25 dl/g sample B not run 1.32 dl/g 2.05 dl/g Hexane, 25°C (a) What is the Mn of sample B? (b) What are the Mark-Houwink-Sakurada parameters (K' and a) acetone and in hexane?

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Two samples with narrow molecular weight distributions are prepared of a new polymer. Some measurements are made in acetone and in hexane.
sample A in acetone have Mn (osmotic pressure) 85000
Sample A
Acetone, 25°C
Parameter
Second viral coeff.
Intrinsic viscosity
Intrinsic viscosity
0
0.87 dl/g
1.25 dl/g
sample B
not run
1.32 dl/g
2.05 dl/g
Hexane, 25°C
(a) What is the Mn of sample B?
(b) What are the Mark-Houwink-Sakurada parameters (K' and a) acetone and in hexane?
Transcribed Image Text:Two samples with narrow molecular weight distributions are prepared of a new polymer. Some measurements are made in acetone and in hexane. sample A in acetone have Mn (osmotic pressure) 85000 Sample A Acetone, 25°C Parameter Second viral coeff. Intrinsic viscosity Intrinsic viscosity 0 0.87 dl/g 1.25 dl/g sample B not run 1.32 dl/g 2.05 dl/g Hexane, 25°C (a) What is the Mn of sample B? (b) What are the Mark-Houwink-Sakurada parameters (K' and a) acetone and in hexane?
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