Use the following Lewis diagram for diethyl ether to answer the questions: H H H -C C H- 1 2 H H H H Remember that geometry refers to the geometry defined by the atoms, not the electron pairs. The geometry about atom C1 is | The ideal value of the C-O-C angle at atom O, is degrees. The geometry about atom C3 is Submit Answer Retry Entire Group No more group attempts remain

Use the following Lewis diagram for diethyl ether to answer the questions: H H H -C C H- 1 2 H H H H Remember that geometry refers to the geometry defined by the atoms, not the electron pairs. The geometry about atom C1 is | The ideal value of the C-O-C angle at atom O, is degrees. The geometry about atom C3 is Submit Answer Retry Entire Group No more group attempts remain

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter3: Atomic Shells And Classical Models Of Chemical Bonding

Section: Chapter Questions

Problem 60P

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The molecular ion S3N3 has the cyclic structure All SN bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is 0.375 and on each S atom is +0.041 . Show that this result is consistent with the overall +1 charge on the molecular ion.
A paper published in the research Journal Science in 2007 (S. Vallina and R. Simo, Science, Vol. 315, p. 506, January 26, 2007) reported studies of dimethylsulfide (DMS), an important green-house gas that is released by marine phytoplankton. This gas represents the largest natural source of atmospheric sulfur and a major precursor of hygroscopic (i.e., cloud-forming) particles in clean air over the remote oceans, thereby acting to reduce the amount of solar radiation that crosses the atmosphere and is absorbed by the ocean. (a) Sketch the Lewis structure of dimethylsulfide, CH3SCH3, and list the bond angles in the molecule. (b) Use electronegativities to decide where the positive and negative charges lie in the molecule. Is the molecule polar? (c) The mean seawater concentration of DMS in the ocean in the region between 15 north latitude and 15 south latitude is 2.7 nM (nanomolar). How many molecules of DMS are present in 1.0 m3 of seawater?
For each of the following molecules or molecular ions, give the steric number, sketch and name the approximate molecular geometry, and describe the direction of any distortions from the approximate geometry due to lone pairs. In each case, the central atom is listed first and the other atoms are all bonded directly to it. (a) TeH2 (b) AsF3 (c) PCl4+ (d) XeF5+
Methanethiol (CH4S) No. of electrons in structure _____ No. of valence electrons _____ Structure is ___________
For each of the following molecules, complete the Lewis structure and use the VSEPR model to determine the bond angles around each central atom. Note that the drawings are only skeleton structures and may depict the angles incorrectly.
Consider the following flat drawing of methane (CH4) . a. What is HCH bond angle implied by this drawing if you assume it is flat? b. Are the electron domains of this flat CH4 spread out as much as possible? c. Use model materials to make a model of CH4 (methane). If you assembled it correctly, thefour bonds (bonding electron domains) of your model will be 109.5° apart. d. In which representation, the drawing above or the model in your hand (circle one) are theH’s of CH4 more spread out around the central carbon? e. Confirm that your model looks like the following drawing. The wedgebond represents a bond coming out of the page, and the dash bondrepresents a bond going into the page f. You will often see methane drawn as if it were flat (like on the previous page). Why is thismisleading, and what is left to the viewer’s imagination when looking at such a drawing?
For each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name acetic acid dimethyl ether compound hypobromous acid formula or Lewis structure H :0: H-C-C-O-H H H H-C-0-C H H H T HBrO | H Between molecules of the compound? yes O O no O yes no yes hydrogen-bonding force no Between molecules of the compound and molecules of water? O O yes no yes no yes no X
ences to STU JO papaaU II :X:Y: The Lewis representation above depicts a reaction between a halogen (blue) and a main-group element from group |(red). In this representation, each Y atom needs | with atoms of X. electron(s) to complete its octet, and gains these electrons by forming bond(s) There are unshared electron pair(s) and bonding electron pair(s) in the product molecule. The bonds in the product are
||| = 43°F Clear O ELECTRONIC STRUCTURE AND CHEMICAL BONDING Predicting the arrangement of electron groups around the centr... Answer the questions in the table below about the shape of the chlorine pentafluoride (CIF) molecule. How many electron groups are around the central chlorine atom? Note: one "electron group" means one lone pair, one single bond, one double bond, or one triple bond. What phrase best describes the arrangement of these electron groups around the central chlorine atom? (You may need to use the scrollbar to see all the choices.) Explanation Check 10 (choose one) (choose one) linear bent T-shaped trigonal planar trigonal pyramidal square planar square pyramidal tetrahedral sawhorse trigonal bipyramidal octahedral Q Search 0/3 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center www.OTAPETY Accessibi
tR-XZxj_1SoekWMaP1As1fEhnC179H4SICzl1mdWKpKlvbF3amiKazP. OF ORGANIC MOLECULES Drawing a Lewis structure for a simple organic molecule from a. GE OOD D Draw a Lewis structure of the molecule that matches the description below. All non-H atoms should have full octets, and all formal charges should be zero. Unless you're told otherwise, assume there are no rings in the molecule. Description: The molecule is composed of 10, 4H's, and 2C's and it contains a C-C single bond. Click and drag to start drawing a structure. 2021 McGraw-Hill Education All Rights Reseved Terms of Uhe Pcy Check Explanation
Is this a reasonable structure? If not, why not? molecule proposed Lewis structure O Yes, it's a reasonable structure. :F : O No, the total number of valence electrons is wrong. CIF 3 The correct number is:U .. .. : F Cl F: O No, some atoms have the wrong number of electrons around them. - The symbols of the problem atoms are: U O Yes, it's a reasonable structure. :0: No, the total number of valence electrons is wrong. .. .. XeO4 :0 - Xe -0: The correct number is:U No, some atoms have the wrong number of electrons around them. :0: The symbols of the problem atoms are: Yes, it's a reasonable structure. No, the total number of valence electrons is wrong. I, The correct number is: U No, some atoms have the wrong number of electrons around them. O :
Use the Lewis dot structure (make sure you show all electron pairs) to predict the electronic geometry_(EG) and the shape of the molecule H2O. O EG - bent; shape - bent O EG - trigonal planar; shape lincar O EG- tetrahedral; shape - bent O EG - tetrahcdral; shape trigonal pyramidal O EG - trigonal bipyramidal; shape - tetrahedral