What reagents could be used to carry out the following syntheses?Complete the syntheses by dragging the labels to the appropriate targets.1. H₂, Lindlar catalyst2.RCOOH01. R₂BH/THF2. HO, H2O2, H₂ORCH2CH3H₂O/H2SO4, HgSO4RCH=CH2RCH-CH2RCHCH3excess HBrBrRC CHBrexcess H₂, Pd/CRCCH3H2/Lindlar catalystBr1 equiv HBrRC=CH21.H2/Lindlar catalyst2. HBrBrRCCH30RCH2CHResetHelp

Step 1: Information: Markovnikovs Rule : In an addition reaction the negative part of reagent goes…

Answered: What reagents could be used to carry…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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6. For the following reactions, predict the major and minor products. Label each. 1. BH₂/THF 2. H₂O₂, OH, H₂O 1. Hg(OAC)₂, H₂O 2. NaBH4
Select the correct reaction. O a. O b. ос Od. o e. 1. LAH OH OH OH OH OH OH 2. PCC 3. CH3CH2Li 4. H3O+ 1. SOCI₂ 2. (CH3CH2)2CuLi 3. H3O+ 1. CH3CH2OH, HA 2. CH3CH2MgBr 3. H3O+ 1. CH3CH2NH2, DCC 2. LAH 1. SOCI₂ 2. CH3CH2Li 3. H3O+ OH of OH of OH
7. Reaction Scheme. NH₂ NH2 or two differnet methods (no same steps/reagents) C5H12N2 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO
3. The following three SNAR transformations follow different mechanisms. Draw an intermediate or transition state for each reaction that relates the correct mechanism. Write a short sentence as to why that is the correct intermediate for the reaction. Reaction 1: Reaction 2: NO2 NO2 NO₂ + NaOMe NO2 + NaOH2 1. aq NaHCO3. 100 C 2. H₂O+ OMe NO2 NO₂ OH ŇO₂ NO2 Reaction 3: CFa Br CF3 8--2 + NaNH2 NH3 NH₂ Intermediate/transition state Intermediate/transition state Intermediate/transition state
Select the appropriate starting material which will give the product cleanly. The starting material is never the same as the product of that reaction sequence. Starting material 1 1. BH3 2. H2O2, NaOH, H₂O 3.TsCI, Imidazole 4. KOtBu 1. HBr Starting material 2 A Br B OH C 2. NaOMe 3. HBr Br D Br E F Starting material 3 (2 possibilites) 1. KOtBu 2. NBS (1 equiv) Br Starting material 1 is Starting material 2 is Starting material 3 is [Choose ] CAAG BEAGEADDHER [Choose ] [Choose] A or B A or G G or H B or H F A or D D or G E or F Br OH G H No new data to save. Last che
What is the product of the following sequence of reactions? CHO NACN H3O*, heat HCI OH OH .CO2H .CN CO2H `CN Он ÓH II IV %3D
HO .OH cat. H2SO4 H₂O cat. H2SO4 Complete both mechanisms above. BRIEFLY explain how the different reaction conditions (in the presence of acid) result in different products being formed. How does equilibrium play a role?
Identify the correct first mechanism step and final product of the reaction shown. 1. ВНз, THF 2. Н2О2, ОН" mechanism step final product H-BH2 OH А. H-BH2 H-BH2 OH C. H-BH2 LBH2 D. OH B.
SECTION 6: Show the mechanism of each reactions with arrows and intermediates form as in a. b. C. HBr Br₂ Cl₂, H₂O Br Br CI Br OH
In each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) 4) DEET (the active ingredient in over the counter insect repellant) 5) Answer Bank Mg, Et,0 HN(CH, CH, ), (1 equiv.) H,O* CH,COOH CH,CH,NH, CH,CH, Br NH(CH,CH,),(2 cquiv.) НСООСH, H,CO НСООН CH, CH, OH NaCN NaNH, Br,, FeBr, SOCI, CO,
Chemistry 4. Predict the structure of all the intermediates in the synthesis of the following triol. SOCI₂ 1. Mg Br 2. CO₂ KOH 1. Br₂, H* 2. Pyridine | LAH OH OH HO DIBAL-H
Which products are most likely to form in this reaction? NH2 H2N NaNH2 NH2 liq. NH3 II O1, II & II O II & II O1& || OI & II

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