When do you use NBS vs. Br2 in bromination? I know you can use Br2 and heat for free radical "markovnikov" addition, and you can use Br2 and peroxide for anti-Markovnikov addition, but then what is the purpose of NBS?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions
Section19.SE: Something Extra
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When do you use NBS vs. Br2 in bromination? I know you can use Br2 and heat for free radical "markovnikov" addition, and you can use Br2 and peroxide for anti-Markovnikov addition, but then what is the purpose of NBS?

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