When the rate for the reaction2NO+ 02 NO,was studied, the rate was found to double when the O₂ concentration was doubled whilethe NO concentration was unchanged. It was also found that the rate quadruples whenthe NO concentration is doubled while the O, concentration is unchanged.o What is the rate law expression for this reaction? PTwo mechanisms were proposed for this reaction as shown below.PROPOSAL IStep 1:Step 2:NO + O₂NO NOPROPOSAL IIStep 1Step 2Step 3NO NO0₂ + N₂O₂N₂0₂NO:NO,N₂O₂N₂O₁NO₂(fast)NO, (alem, RDS)(slow, RDS)(test)NO₂ (fast)b. Write a predicted rate low for each proposed mechanism. In your predicted rate law,make sure no intermediates are present in the overall expressionc. Which proposed mechanism I or II agrees with the rate kw expression that youdetermined above? You must also explain your reasoning or no credit will be given Place

Note - Since the given question is a multiple question, hence I solved first question according to…

When the rate for the reaction 2NO+ 0 2 NO, was studied, the role was found to double when the O₂ concentration was doubled while the NO concentration was unchanged. It was also found that the rate quadruples when the NO concentration is doubled while the O, concentration is unchanged.

When the rate for the reaction 2NO+ 0 2 NO, was studied, the role was found to double when the O₂ concentration was doubled while the NO concentration was unchanged. It was also found that the rate quadruples when the NO concentration is doubled while the O, concentration is unchanged.

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter12: Chemical Kinetics

Section: Chapter Questions

Problem 9RQ

See similar textbooks

Related questions

Q: A photon has a frequency of 8.97 x 108 Hz. What is the energy of this photon in Joules? (h = 6.626 x…

A: Given, Frequency of a photon (v) = 8.97 × 108 Hz = 8.97 × 108 s-1 Energy of a photon (E) = ? Note:…

Q: The mechanism proposed for the oxidation of iodide ion by the hypochlorite ion is shown below. Step…

Q: [Modified] A compound with molecular mass 427.35 g/mol was dissolved in a 5-mL volumetric flask. A…

Q: How many g of Si3O5 are in 0.094 mol Si3O5?

Q: he pH of a 0.82M solution of hypobromous acid (HBrO) is measured to be 4.36. alculate the acid…

Q: Draw Newman structures for the structure shown below through the highlighted bond that correspond to…

A: It involves six structures.

Q: Describe how you would prepare 250 mL of a 2.25 M solution of hydrochroic acid solution starting at…

A: For making 2.25 M solution we have to dilute 12 M solution by adding water. For find out water (mL)…

Q: you have 0.65 moles of penicillin, how many penicillin molecules do you have?

A: Avagadro number is used to calculate number of molecules/atom present in one mole of compound.…

Q: Select the correct name for the compound, including the correct (E) or (Z) designation where…

Q: theoretical Be sure your answer has the correct number of significant digits in it. yield of carbon…

A: One mole of butane react with oxygen and produce 4 mole of carbon dioxide and 5 mole of water…

Q: How is this absorption of light related to the molecular shape of the atmospheric gases? Their…

A: In case of molecule to absorb light or to be IR active, It should have a dipole moment, i.e.; it…

Q: Consider the following balanced chemical equation. 5 F2 (g) + Br2 (l) → 2 BrF5 (l) 0.789…

A: Answer: This question is based on stoichiometric calculation where we have to convert the moles of…

Q: where does the formula at the start of step 5 come from?

A: The formula in step-5 comes from the conversion factor as shown below: From the previous steps, we…

Q: Which of the following pairs co the same intermolecular forces NH₂ and CH4 H₂S and CH₂ сни H ₂0…

A: Intermolecular forces, often abbreviated to IMF, are the attractive and repulsive forces that arise…

Q: Study the following phase diagram of Substance X. pressure (atm) 20- 10- solid 100 liquid gas 200…

A: Phase diagram gives the idea about relationship of temp and pressure.

Q: How much HCO2H is obtained by reacting 1.00 g FeS, 0.50 g H2S, and 0.50 g CO2 if the reaction…

Q: = ⒸORGANIC FUNCTIONAL GROUPS Naming alkyl halides Name these organic compounds: Explanation CI…

A: All these compounds are examples of saturated halides consisting of several chlorine, iodine and…

Q: The major product of the following reaction is OH H₂SO4 heat

Q: Given the following equation, determine how many grams of iron that can be produced from 57.6 grams…

A: Answer:- This question is answered by using the simple concept of stoichiometry which involves the…

Q: When 7.59 grams of sodium hydroxide (NaOH) are dissolved in 80.0 grams of water at 25.0 °C in an…

A: The Enthalpy Change for the 1st part can be calculated by the formula:- Heat absorbed in the…

Q: Given a solution of 0.13 M formic acid (HCOOH) with a pH of 2.4, calculate the acid’s Ka.

Q: How much of natural uranium is U-235? Group of answer choices 0.7% 13 % 33 % 99.3 % 100%

Q: 7. Which compound is more soluble in water-CH₂COOH or CH CH CH CH? Explain. 8. Which compound is…

Q: Gaseous butane (CH₂(CH₂),CH₂). theoretical yield of water formed from the reaction of 1.7 g of…

A: One mole of butane react with oxygen and produced 4 mole of carbon dioxide and 5 mole of water

Q: The solubility of Ag₂SO4 is measured and found to be 4.95 g/L. Use this information to calculate a…

Q: Calculate the original pressure (atm) of 25 mL of air, which has a pressure of 3.3 atm when its…

Q: What mass of CO2 (in Kg) does the combustion of a 12-gallon tank of gasoline release into the…

A: volume of gasoline = 12-gallon =45.4249 L= 45.4249 x 103 mL density of gasoline = 0.70 g/mL

Q: how did you get 0.0686 from 0.0096= .0140 x V

A: The complete mathematical operation getting 0.0686 L is shown below:

Q: When a red light with a wavelength of 670 nm shines on a piece of metal, an electron is ejected.…

Q: 8. Hydrazine, N₂H4, is a rocket fuel. Calculate the AH°rn when 1 mole of hydrazine is combusted…

Q: 1 4 7 +/- Calculate the frequency in hertz of electromagnetic radiation that has a wavelength of…

A: This is a mathematical calculation where now we have to find out the frequency using the expression…

Q: Redox titration: What volume (mL) of Na2S2O3 (0.215 M) solution is required to completely react with…

Q: A 2.85 g sample of NaCl and CaCl₂ was dissolved in water, and an excess of AgNO3 was added to…

A: Given, 2.85 g sample of NaCl and CaCl2 dissolved in water and excess AgNO3 to give 7.20 g of AgCl…

Q: H Н х н Н .05 Н.

Q: What is the potential of a copper electrode in a 0.010 M solution of CuSO4? Select one: a. -0.798 V…

A: Electrode potential can be determined by the reduction electrode formula:-

Q: Give a clear handwritten answer with explanation..give the answer only c part ?

A: c.) First we need to calculate the moles of both reactants and determine the limiting reagent. Then…

Q: Calculate the wavelength in meters of electromagnetic radiation that has a frequency of 1.60 x 108…

A: Answer:- This question is answered by using the simple concept of calculation of wavelength using…

Q: What volume of each of the following acids will react completely with 80.00 mL of 0.200 M NaOH? a.…

A: The reaction between an acid and base is known as neutralization reaction In a neutralization…

Q: What volume of 3.5 M HCl is needed to neutralise 25 mL of 2.6 M KOH solution in a titration? HCl…

Q: If 18.0 mL of 9.22x10-4 M Ca(CH3COO)2 are added to 18.0 mL of 7.80x10-5 M (NH4)2SO4, will solid…

A: Answer: For the precipitation of sparingly soluble salt to begin its ionic product should be equal…

Q: (FeS2(s)), which reacts with molecular oxygen to produce Fe2O3(s) and SO2(g). Write the balanced…

A: Balancing is done to make atom of all the elements equal in reactant and product side.

Q: 1. Indicate which of the following elements/ions best fits each category: S S²- Se Se²- Si Sn Sn4+…

A: Ionization energy is the energy required to remove the most loosely bound electron form an isolated…

Q: Draw the products of the reaction.

Q: 07 6₂ П CH2OH Br Br d. S -H CI H CH₂CH3 C/ RXO H H3C/ Br C Br 2 Br H CH₂OH Xx O CI Br CH₂CH3 R CI Br…

A: The absolute configuration (R/S) of an organic compound can be determined using Cahn-Ingold-Prelog…

Q: 6. a) Circle which substrate undergoes the fastest solvolysis reaction with methanol (CH3OH): CH3I…

Q: The following are metal pairs representing electrodes in theoretical voltaic cells. Which pair is…

A: (a) Cu EMF= +0.34 V Pb EMF= -0.13 V In electrochemical series, the element which has more negative…

Q: Determine the energy of a photon with a wavelength of 404 nm.

A: The energy of a photon is given by the formula E = hcλ E = energy of photon h = Planck's constant…

Q: The activity of Ba2+ is closest to its molarity when the ionic strength is equal to what? infinity,…

A: Activity is defined as the ability of particular ion concentration in a given solution.

Q: 115 A rocket can be powered by the reaction between dinitro- gen tetroxide and hydrazine: N₂O₁ (1) +…

A: 4.115) Given, Nitrogen tetraoxide reacts with hydrazine to form nitrogen gas and water N2O4(l) +…

Q: 4. You have a solution of 0.2064 M cobalt(II) chloride. (a) How many moles of solute are contained…

Question

When the rate for the reaction
2NO+ 0
2 NO,
was studied, the rate was found to double when the O₂ concentration was doubled while
the NO concentration was unchanged. It was also found that the rate quadruples when
the NO concentration is doubled while the O, concentration is unchanged.
o What is the rate law expression for this reaction? P
Two mechanisms were proposed for this reaction as shown below.
PROPOSAL I
Step 1:
Step 2:
NO + O₂
NO NO
PROPOSAL II
Step 1
Step 2
Step 3
NO NO
0₂ + N₂O₂
N₂0₂
NO:
NO,
N₂O₂
N₂O₁
NO₂
(fast)
NO, (alem, RDS)
(slow, RDS)
(test)
NO₂ (fast)
b. Write a predicted rate low for each proposed mechanism. In your predicted rate law,
make sure no intermediates are present in the overall expression
c. Which proposed mechanism I or II agrees with the rate kw expression that you
determined above? You must also explain your reasoning or no credit will be given Place

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The label on a bottle of 3% (by volume) hydrogen peroxide, H2O2, purchased at a grocery store, states that the solution should be stored in a cool, dark place. H2O2decomposes slowly over time, and the rate of decomposition increases with an increase in temperature and in the presence of light. However, the rate of decomposition increases dramatically if a small amount of powdered MnO- is added to the solution. The decomposition products are H2O and O2. MnO2 is not consumed in the reaction. Write the equation for the decomposition of H2O2. What role does MnO2 play? In the chemistry lab, a student substituted a chunk of MnO2 for the powdered compound. The reaction rate was not appreciably increased. WTiat is one possible explanation for this observation? Is MnO2 part of the stoichiometry of the decomposition of H2O2?
Use the data provided to graphically determine the order and rate constant of the following reaction: SO2CI2SO2+CI2 Time(s) 0 5.00103 1.00104 1.50104 [SO2CI2] (M) 0.100 0.0896 0.0802 0.0719 Time(s) 2.50104 3.00104 4.00104 [SO2CI2] (M) 0.0577 0.0517 0.0415
The rate constant, k, at 25 C is 0.27/h for the reaction Pt(NH3)2Cl2(aq) + H2O() [Pt(NH3)2(H2O)Cl]+(aq) + Cl(aq) and the rate equation is Reaction rate = k[Pt(NH3)2C12] Calculate the rate of reaction when the concentration of Pt(NH3)2Cl2 is 0.020 M.
In the nuclear industry, chlorine trifluoride is used to prepare uranium hexafluoride, a volatile compound of uranium used in the separation of uranium isotopes. Chlorine trifluoride is prepared by the reaction CI2(g)+3F2(g)2CIF3(g). Write the equation that relates the rate expressions for this reaction in terms of the disappearance of Cl2 and F2 and the formation of CIF3.
Consider a reaction of the type aA products, in which the rate law is found to he rate = k[A]3 (termolecular reactions are improbable but possible). If the first half-tife of the reaction is found to he 40. s, what is the time for the second half-life? Hint: Using your calculus knowledge, derive the integrated rate law from the differential rate law for a tennolecular reaction: Rate=d[A]dt=k[A]3
The mechanism for the reaction of CH3OH and HBr is believed to involve two steps. The overall reaction is exothermic. Step 1: Fast, endothermic CH3OH + H+ CH3OH2+ Step 2: Slow CH3OH2+ + Br CH3Br + H2O (a) Write an equation for the overall reaction. (b) Draw a reaction coordinate diagram for this reaction. (c) Show that the rate law for this reaction is Rate = k[CH3OH][H+][Br].
The rate constant for the ?rst-order decomposition at 45 C of dinitrogen pentoxide, N2O5, dissolved in chloroform, CHCI3, is 6.2104 min-1. 2N2O54NO2+O2 What is the rate of the reaction when [N2O5] = 0.40 M?
For each of the following reaction diagrams, estimate the activation energy (Ea) of the reaction:
Nitramide, NO2NH2, decomposes slowly in aqueous solution according to the following reaction: NO2NH2(aq) N2O(g) + H2O() The reaction follows the experimental rate law Rate=k[NO2NH2][H3O+] (a) What is the apparent order of the reaction in a pH buffered solution? (In a pH buffered solution, the concentration of H3O+ is a constant.) (b) Which of the following mechanisms is the most appropriate for the interpretation of this rate law? Explain. (Note that when writing the expression for K, the equilibrium constant, [H2O] is not involved. See Chapter 15.) Mechanism 1 NO2NH2K1N2O+H2O Mechanism 2 NO2NH2+H3O+k2k2NO2NH3++H2O(rapidequilibrium) NO2NH3+k3N2O+H3O+(rate-limitingstep) Mechanism 3 NO2NH2+H2Ok4k4NO2NH+H3O+(rapidequilibrium)NO2NHk5N2O+OH(rate-limitingstep)H3O++OHk62H2O(veryfastreaction) (c) Show the relationship between the experimentally observed rate constant, k, and the rate constants in the selected mechanism. (d) Based on the experimental rate law, will the reaction rate increase or decrease if the pH of the solution is increased?
The reaction of compound A to give compounds C and D was found to be second-order in A . The rate constant for the reaction was determined to be 2.42 L/mol/s. If the initial concentration is 0.500 mol/L, what is the value of t1/2?