Which of the following are correct expressions for the overall rate constant? | k = k3[(K₂)/(K-2)]√{([(K₁)/(k-₁)])} ✓k= ([(k₂k3)/(K-2)])√{{[(K₁)/(k_₁)])[¹/2]} ✓k= ([(k₁)/(k-₁)])[1/2] ([(K₂)/(K-2)])K3 ✓k = [(k₁[¹/2]k₂k3K4)/(k-1 [¹/2]k-2)] ✓k = [(k3k₂V{k₁})/(k_₂V{k_1}}]

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.59PAE: Can a reaction mechanism ever be proven correct? Can it be proven incorrect?
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Which of the following are correct expressions for the overall rate constant?

Which of the following are correct expressions for the overall rate constant?
| k = k3[(K₂)/(k_2)]√{([(K₁)/(k-₁)])}
✓k = ([(k₂k3)/(K-2)])√{([(k₁)/(k-₁)]}][ 1/2]}
✔] k = ([(k₁)/(k-1)])[¹/2] ([(K₂)/(K-₂)])k3
✓ | k = [(k₁[¹/2]k₂k3K4)/(k_1 [1/2]k-2)]
✓k = [(K3k₂V {k₁})/(k_2V{k_1})]
Transcribed Image Text:Which of the following are correct expressions for the overall rate constant? | k = k3[(K₂)/(k_2)]√{([(K₁)/(k-₁)])} ✓k = ([(k₂k3)/(K-2)])√{([(k₁)/(k-₁)]}][ 1/2]} ✔] k = ([(k₁)/(k-1)])[¹/2] ([(K₂)/(K-₂)])k3 ✓ | k = [(k₁[¹/2]k₂k3K4)/(k_1 [1/2]k-2)] ✓k = [(K3k₂V {k₁})/(k_2V{k_1})]
CO(g) + Cl₂(g) → CoCl₂(g)
The above reaction obeys the mechanism:
Cl₂ =
2CI Fast equilibrium
CI + CO
COCI Fast equilibrium
COCI + Cl₂
COCl₂ + Cl
Slow
2CI
Fast
K4, Cl₂
Transcribed Image Text:CO(g) + Cl₂(g) → CoCl₂(g) The above reaction obeys the mechanism: Cl₂ = 2CI Fast equilibrium CI + CO COCI Fast equilibrium COCI + Cl₂ COCl₂ + Cl Slow 2CI Fast K4, Cl₂
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