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Please explain which carbonation will rearrange and why
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- b) DRAW THE product of each of the following reactions? DRAW expected product stereochemistry, where NEEDED TO b) חוו H3C- Pd(OAc)2 Ag2CO3 dppe H OBn 1. B2H6, THF CH3 CH3 2. NaOH, H2O2 B 09) Draw the conformer structure, Newman projection, before elimination and the elimination product of the following reaction: Br CH3ONA HSN1 reactions undergo carbocation rearrangements, but E1 reactions do not because the carbocation intermediate does not last as long during the elimination process. True O False
- For each reaction, decide whether substitution or elimination (or both) is possible, andpredict the products you expect. Label the major products. chlorocyclohexane + NaOCH3 in CH3OHElimination occurs when (Z)-3-bromohex-3-ene is treated with NaNH2. Under the same conditions, 1-bromocyclohexeneundergoes elimination much more sluggishly. Explain whyWhat would be the major product of the following reaction? O CH3 || C6H5C-CHCH3 + D20 A) B) C) D) E) O CD3 C6H5C-CHCH3 O CH3 1-1 C6H5C-CDCH3 O CH3 C6D5C-CDCH3 O CD3 | | C6H5C-CDCD3 OD - C6H5CDCHCH3 CH3 OD room temp. ?
- ONZ IS ON Determine which substitution mechanism occurs and draw the products, including stereochemistry. + -OCH3 DMSO Br H + CH3OH Br CH,CH, CH3Draw a reaction mechanism illustrating the transition state structure and stereochemistry of the resulting product (if any).a. (R)-2-bromobutane + -OCH3 → (SN2)b. (S)-3-bromo-3-methylhexane + methanol → (SN1)c. 2-Chloro-2-methylhekxane + -OH → (E1)In EAS bromination reactions, a -NHCOCH3 substituent on the aromatic ring is: O an activator and an o,p-director. O a deactivator and a m-director. an activator and a m-director. NHCOCH3 catalyzes the 1,2 addition of bromine across the double bond O a deactivator and an o,p-director.