Why is the concentration ratio the same for the calculation of pKa2? "The pKa values of a compound with two ionizable groups are pK1 = 4.10 and pK2 between 7 and 10. A biochemist has 10 mL of a 1.0 M solution of this compound at a pH of 8.00. She adds 10.0 mL of 1.00 M HCl, which changes the pH to 3.20. What is pK2?"

Why is the concentration ratio the same for the calculation of pKa2? "The pKa values of a compound with two ionizable groups are pK1 = 4.10 and pK2 between 7 and 10. A biochemist has 10 mL of a 1.0 M solution of this compound at a pH of 8.00. She adds 10.0 mL of 1.00 M HCl, which changes the pH to 3.20. What is pK2?"

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter15: Additional Aqueous Equilibria

Section: Chapter Questions

Problem 105QRT: Apatite, Ca5(PO4)3OH, is the mineral in teeth. On a chemical basis explain why drinking milk...

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Apatite, Ca5(PO4)3OH, is the mineral in teeth. On a chemical basis explain why drinking milk strengthens young children’s teeth. Sour milk contains lactic acid. Not removing sour milk from the teeth of young children can lead to tooth decay. Use chemical principles to explain why.
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Phosphoric acid (H₃PO₄) is a triprotic acid with pKa values of 2.12, 7.21, and 12.32. It is a useful buffer solution for pH values near the pKa values. You have a 0.100 M solution of phosphate buffer with a pH of 2.50. How many mL of 0.500 M NaOH solution must be added to 1.00 L of this buffer solution to convert it to a buffer at pH 7.70? Carbonic acid, H₂CO₃ is a diprotic acid with Ka1 = 4.3 × 10⁻⁷ and Ka2 = 5.6 × 10⁻¹¹. What is the pH of a 0.62 M solution of carbonic acid? A diprotic acid, H₂A, has Ka1 = 3.4 × 10⁻⁴ and Ka2 = 6.7 × 10⁻⁹. What is the pH of a 0.20 M solution of H₂A? What is the pH of a buffer made from 0.220 mol of HCNO (Ka = 3.5 × 10⁻⁴) and 0.410 mol of NaCNO in 2.0 L of solution?
Consider a biochemical reaction that is taking place in a 0.1 M buffer. The initial pH is 7.4, and the pKa of the buffer is 7.2. If, in a final reaction volume of 1.0 mL, 10 micromol of protons are generated, what would be the final pH of the solution?
Use the following pKa values of phosphoric acid H3PO4: pka1 = 2.15 pka2 = 7.2 pka3 = 12.4 Assume 0.2 mol of Na3PO4 and 0.5 mol of Na2HPO4 are dissolved in 1 Liter of water. Part A. What is the pH of this solution ?
Suppose a biochemist has 10 mL of a 1.0 M solution of a compound with two ionizable groups at a pH of 7.80. She adds 10.0 mL of 1.0 M HCl, which changes the pH to 4.20. The pKą value of one of the groups is pK₁ = 4.10 and it is known that pK₂ is between 7 and 10. What is the exact value of pK₂? pK₂ =
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There are many organic acids and bases in our cells, and their presence modifies the pH of the fluids inside them. It is useful to be able to assess the pH of solutions of acids and bases and to make inferences from measured values of the pH. A solution of equal concentrations of lactic acid and sodium lactate was found to have pH= 3.08. (a) What are the values of pKa and Ka of lactic acid? (b) What would the pH be if the acid had twice the concentration of the salt?
You need a buffer with a pH = 12. You have solid Na3PO4and 1.00 M HCl, and water. The buffer must have a total phosphate concentration of 0.750 M and have a total volume of 500 mL. Calculate the amount of Na3PO4(in grams), the volume of 1.00 M HCl, and volume of water necessary to make the desired buffer. The pKa values of H3PO4 are pKa1=2.14, pKa2=7.20, pKa3=12.37 What are the Grams of Na3PO4
The pKa values of a compound with two ionizable groups are pK1 =4.10 and pK2 between 7 and 10. A biochemist has 10 mL of a 1.0 M solution of this compound at a pH of 8.00. She adds 10.0 mL of1.00 M HCl, which changes the pH to 3.20. What is pK2? Thank you for your help.