1. The following data was obtained from decomposition of nitrogen oxide (NO). 2HX Hz + X2 T(K) 703 733 759 791 811 836 865 k (L mol-¹s-¹) 0.011 Find; 0.035 0.105 0.343 0.790 2.14 4.95 (a) The activation energy, Ea. (b) The Arrhenius constant, A (c) The collision frequency, ZAA (d) The following mechanism was suggested for the reaction. Is the mechanism meet with the order of reaction? X2 X+X Fast X+H2 HX + H Slow H + X₂ → X + H2 Fast

Chemistry for Engineering Students
4th Edition
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Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.58PAE
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1.
The following data was obtained from decomposition of nitrogen oxide (NO).
2HX
H2 + Xz
T(K)
703
733
759
791
811
836
865
k (L mol-¹s-¹) 0.011 0.035
0.105 0.343 0.790
2.14
4.95
Find;
(a) The activation energy, Ea.
(b) The Arrhenius constant, A
(c) The collision frequency, ZAA
(d) The following mechanism was suggested for the reaction. Is the mechanism meet
with the order of reaction?
X2 X + X
Fast
X + H2
HX2 X + H₂
→ HX + H
Slow
Fast
Transcribed Image Text:1. The following data was obtained from decomposition of nitrogen oxide (NO). 2HX H2 + Xz T(K) 703 733 759 791 811 836 865 k (L mol-¹s-¹) 0.011 0.035 0.105 0.343 0.790 2.14 4.95 Find; (a) The activation energy, Ea. (b) The Arrhenius constant, A (c) The collision frequency, ZAA (d) The following mechanism was suggested for the reaction. Is the mechanism meet with the order of reaction? X2 X + X Fast X + H2 HX2 X + H₂ → HX + H Slow Fast
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