100- "H NMR (phenacetin) 3H 3H 50- 2H 2H 2H 4000 3500 3000 2500 2000 1500 1000 500 Wavenumber (cm") % Transmitance

Q: The compound obtained by treating propan-1-ol with PCC followed by excess of ethanol in presence of…

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Q: Treating trimethylamine with 2-chloroethyl acetate gives acetylcholine as its chloride.…

A: Trimethylamine reacts with 2-chloroethylacetate by SN2 mechanism. Thus the bond breaking and bond…

Q: (A true story.) A drug user responded to an ad placed by a DEA informant in a drug-culture magazine.…

A: (a) When methylamine hydrochloride reacts with phenylacetone, it results in formation of amine.…

Q: 2.1 Use electronic factors (resonance and inductive effects) to rank the following compounds in…

A: Acidity of the compound will depend upon the tendency of a compound to donate its H+ ion.  Comparing…

Q: An amine of unknown structure contains one nitrogen and nine carbon atoms, as well as at least one…

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Q: A compound of molecular formula C5H12O2 compound has strong infrared absorption at 3300 to 3400…

A: 1. Degree of unsaturation (D.O.U) :  D.O.U = (2C + 2 - H + N - X ) / 2            = ( 2 x 5 + 2 -…

Q: Following are structural formulas for phenol and cyclohexanol along with the acid dis- sociation…

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Q: Propose a mechanism for the steam hydrolysis of pulegone to the compounds shown.

A: Hydrolysis – Addition of water in a given molecule  is called hydrolysis Hydrolysis is simply the…

Q: A compound with molecular formula C8H8O3 exhibits the following IR, 1H NMR and 13C NMR spectra.…

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Q: Draw the structural formula of the principal organic product formed when benzonitrile is treated…

A: Methyl magnesium bromide reacts with benzonitrile to form an imine salt which then hydrolysed to…

Q: The following compounds (A-D) are isolated from anise and fennel (as well as various related…

A: compound B orC

Q: What are 2-3 organic compounds  that each contain at least one of the following: carboxylic acid,…

A: Organic compounds are any chemical compounds that contain carbon-hydrogen bonds in general. Millions…

Q: Propose a mechanism for this reaction

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Q: Heating compound X with aqueous formaldehyde forms Y (C17H23NO),which has been converted to a…

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Q: When a compound with molecular formula C11H14O2 undergoes acid-catalyzed hydrolysis, one of the…

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Q: Cancer of the prostate is the second leading cause of cancer deaths among American males, exceeded…

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Q: What generalization trends may be extracted from the following series in terms of solubility with…

A: Acid base reaction is faster than other reaction so Base will react first with an acid. Now in set…

Q: Predict the products of reactions of ketones and aldehydes with the followingtypes of compounds, and…

A: SOLUTION: Step 1: Since the question has multiple sub parts, the first three parts are solved. In…

Q: The 1H-NMR spectrum of Compound D of molecular formula C10H12O shows three singlets – δ 2.20 (6H,…

A: In H' NMR number of signals equal to number of sets of equivalent protons number of Sets    Each…

Q: Following is a retrosynthetic analysis for the anthelmintic (against worms) diethylcarbamazine. N.…

A: Diethylcarbamazine is an organic compound used to treat Filariasis. It is formed y treating…

Q: ČOEt 1. EtO-Na+ OEt 3. NAOH, H,O, heat EtO 4. HCI, heat 2-Carbethoxy- 4-Butanolactone…

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Q: The two most general amine syntheses are the reductive amination of carbonyl compounds and the…

A: Amines are the compounds that have NH2 group present in it. The lone pair of nitrogen can be donated…

Q: Substituted phenols show substituent effects similiar to substituted benzoic acids. Should the pKa…

A: The given compound is

Q: Spasmolytol, as its name suggests, is an antispasmodic. Given this retrosynthetic analysis, propose…

A: Spasmolytol  is an antispasmodic drug that used to relieve the pain of involuntary muscle. Salicylic…

Q: Show how to synthesize the following amines from the indicated starting materials below. Each of the…

A: The question is based on the concept of chemical reactions. we have to convert benzene to meta-bromo…

Q: 2-Propylpentanoic acid (valproic acid) is an effective drug for treatment of several types of…

A: Given: 2-Propylpentanoic acid (valproic acid) is an effective drug for treatment of several types of…

Q: Benzoic acid, Ph-COOH (C6H5CO2H), is not soluble in water while it dissolves in ether (diethyl…

A: Benzoic acid ===> Organic Diethyl ether ===> Organic

Q: -NH -OEt H2N 1. EtO Na* 2 CH,CH2OH 2. H,0 - NH -OEt H,N Barbiturates are prepared by treating a…

A: Solution:

Q: 19. Substituted phenols show substituent effects similiar to substituted benzoic acids. Should the…

A: The given compound is In the given compound, the hydroxyl group and long alkyl chain increases the…

Q: Is haloperidol chiral? If so, how many of the possible stereoisomers are formed in this synthesis?

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Q: Given this retrosynthetic analysis, propose a synthesis for the local anesthetic hexylcaine. N. + HO…

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Q: Following are structural formulas for amphetamine and methamphetamine. H NH, CH3 (a) (b) Amphetamine…

A: (a) Treatment of 1-phenylpropan-2-one with ammonia in the presence of sodium cyanoborohydride gives…

Q: Atenolol is a beta blocker medication primarily used to treat high blood pressure and heart-…

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Q: Propose a synthesis for diphenhydramine starting from benzophenone, benzoic acid, and 2-(N,…

A: Synthetic method for diphenhydramine: Benzophenone undergoes reduction using sodium borohydride on…

Q: Which of the following acid derivatives can be hydrolyzed in water spontaneously without acid or…

A: Acid derivatives mainly gives Nucleophillic acyl substitution reaction, in which the group attached…

Q: 2-Phenylindole is prepared from the reaction of acetophenone and phenylhydrazine, a method known as…

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Q: Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You…

A: The structure of p-bromoaniline is shown below.

Q: In the mid-1930s a substance was isolated from a fungus that is a parasite of ryes and other…

A: Given that, lysergic acid diethylamide (LCD, C20H25N3O). It is a weak base, having Kb = 7.6×10-7.…

Q: An amine of unknown structure contains one nitrogen and nine carbon atoms. The 13C-NMR spectrum…

A: Hofmann elimination It is the reaction of amine with β hydrogens and methyl iodide, silver oxide is…

Q: Compound A (CsH18O) forms a phenylhydrazone, but it gives a negative Tollens' test. The IR spectrum…

A: The structure of the unknown compound can be determined with the help of the 13-CNMR, IR, and the…

Q: Treatment of pentanedioic (glutaric) anhydride with ammonia at elevated temperature leads to a…

A: In this question, we will draw the structure of the Product which molecular formula is C5H7NO2  You…

Q: H3C-CH3 The name of following amine compound is N,N-Dimethylaniline, and it is a tertiary aromatic…

A: The first and the foremost step while naming the IUPAC name of an organic compound is the…

Q: Predict the products formed when cyclohexanone reacts with the following reagents. (а) CH;NH2, H*…

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Q: Following is a retrosynthetic analysis for the synthesis of the herbicide (S)-Metolachlor from…

A: The retrosynthetic method is used to predict the starting material from product structure by…

Q: γ-Butyrolactone (C4H6O2, GBL) is a biologically inactive compound that is converted to the…

A: The molecular formula of the given compound is C4H6O2. Information from IR spectrum data: IR…

Q: 1. Predict the products or the reaction of (i) phenylacetaldehyde and (ii) acetophenone with the…

A: Organic reactions are those in which organic reactant react to form organic products.

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.