5. The following reaction forms three possible products. Please indicate which are stereoisomeric and which 2 are the major products. Propose different reaction conditions that would afford a single stereoisomer, show that product. CH3OH CI
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- For each reaction, decide whether substitution or elimination (or both) is possible, andpredict the products you expect. Label the major products. chlorocyclohexane + NaOCH3 in CH3OHYour task is to convert 2-bromobutane to 1-butene in highest yield. Which reagents would you use? O KOH/H2O O KOH/CH,OH O CH3CH2ONA/CH3CH2OH O CH3ONA/CH3OH O (CH3)3COK/(CH3)3COHConsider the reaction below: D D DBr The final product of this reaction has [Select ] a total of [Select] stereoisomer(s). stereocenter(s), and may form
- In light of your answer to Problem 11-74, explain why one of the following isomers undergoes E2 reaction approximately 100 times as fast as the other. Which isomer is more reactive, and why?Consider the reaction below: D D HBr The final product of this reaction has [Select] and may form a total of [Select] Th stereocenters, stereoisomers.The cycloaddition of 2-methylfuran and the unsaturated lactam (see below) yields up to 4 regioisomeric and diastereomeric products, all chiral and racemic. + N-Ph CH3 a) Draw the structure of the 4 possible regio- and diastereomers of this reaction. b) Which compound will be the major product obtained? Explain your answer based on effects of primary and secondary orbital interactions. O 4 possible regio- and diastereomers 80 °C
- Discuss the following nucleophilic substitutions in terms of reaction conditions and stereochemical output. RO. NaCN Br R= H, CH3 Identify the preferred substitution mechanism for the following reactions. CH3 RSH ROH R. X = CI, Br, I R= H, CGH5Draw the mechanism for the following reaction and account for the relative stereochemistry. MeO₂C MeO₂C CO₂Me Pd2(dba)3.CHCI 3 Ph3P, ACOH MeO₂C2) Show the products of the following two reactions, indicating the stereochemistry of the major isomer in each case. H₂C H.CO. OCH, OCH, LOCH, ?
- 6. Provide the structure for the major product formed when the molecule drawn below is treated with each of the following reagents. No need to show the stereochemistry of the product. H₂ Ni 50% H₂SO4 H₂O | 2. Zn, H₂O HBr HOOH HCIA student adds NBS to a solution of 1-methylcyclohexene and irradiates the mixture with a sunlamp until all the NBS has reacted. After a careful distillation, the product mixture contains two major products of formula C7H11Br. Draw the products obtained from each free-radical intermediate.3. When the alkene A was treated with Br₂, the product formed was the epoxide B. Using curved arrows please give the mechanism of this reaction, including any regioselectivity or stereoselectivity. Br₂ 00+00 H₂O