A 35.0 mL of 1.00 x10–2 M Ca2+ was titrated with 0.0250 M EDTA at a pH of 10 and in the presence of 0.0500 M NH3. The formation constant for Ca2+–EDTA is 4.5 x1010. *αY4– = 0.35 at a pH 10; αCa2+ = 0.969 when the concentration of NH3 is 0.0500 M. Calculate the pCa (20pts) a.)   Before equivalence point b.)   At equivalence point

Fundamentals Of Analytical Chemistry
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Chapter17: Complexation And Precipitation Reactions And Titrations
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 A 35.0 mL of 1.00 x10–2 M Ca2+ was titrated with 0.0250 M EDTA at a pH of 10 and in the presence of 0.0500 M NH3. The formation constant for Ca2+–EDTA is 4.5 x1010.

*αY4– = 0.35 at a pH 10; αCa2+ = 0.969 when the concentration of NH3 is 0.0500 M.

Calculate the pCa (20pts)

a.)   Before equivalence point

b.)   At equivalence point

c.)    After equivalence point

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