A picture of 2-methyl-2-propene with the molecular orbitals is shown. Identify the hybridization of the indicated carbon. A) sp B) sp? H3C C) sp H3C" D) sp* E) sp?d?
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- Draw the molecular orbital picture of CH3 - C= C - H. Indicate the type of hybridization on each carbon atom.HHO HH нно H-C- -C- -C -H H-C-C-C-OH a C=Cb b H H H H H H HH Many reactions involve a change in hybridization of one or more atoms in the starting material. In this reaction, determine the hybridization of the indicated atoms in the organic starting material, and determine if they have changed hybridization during the reaction. Atom a: Reactant: Product: Atom b: Reactant: Product: a + H HWrite a bond-line structure for the following compounds. Present correct geometry for sp3, sp2, and sp hybridized carbon atoms (2 points x 2=4 points) 4. а. HO3SCHCHCHCHCH2CH2COOH, both double bonds in this compound have cis geometry
- H. H H Write the carbon atom(s) in numerical order as a comma separated list (e.g. to identify carbon atoms 1, 2 and 4 write "1,2,4"). If there are no carbons with the specified hybridization, write "O" for carbon atom(s) and select "N/A" for the geometry. Carbon atom(s) is(are) sp° hybridized and Carbon atom(s) is(are) sp? hybridized and Carbon atom(s) is(are) sp hybridized and >Draw all constitutional isomers with the molecular formula CsH10 that possess one t bond Specify the hybridization of each carbon atom. H3C CH3 Convert the skeletal drawing of the pharmaceutical Vioxx into a moleculay formula. Identify all sp' hybridized carbons CH,SO, What is the expected geometry around the sulfur atom in diethyl sulfide? CH;CH,-S-CH,CH3 a. linear b. trigonal planar c. tetrahedral2. Account for the bond angle differences between (i) H-C-H (109.5°) in methane and H-S-H (90°); H-C-H (109.5°) and H-O-H (107.5°) in water The H-S-H has two lone pairs; The H-O-H has two lone pairs The H-S-H has no hybridization at p-orbitals; The H-O-H has two lone pairs The H-S-H has two lone pairs; The H-O-H has no hybridization at p-orbitals The H-S-H has no hybridization at p-orbitals; The H-O-H has no hybridization at p- orbitals
- 2) Based on valence bond theory, which statement best describes the electron geometry and hybridization of the central atom(s) in acetylene HCCH? A) The electron geometry of the 2 carbons in acetylene is linear with a sp hybridization. B) The electron geometry of the 2 carbons in acetylene is trigonal planar with a sp2 hybridization. C) The electron geometry of the 2 carbons in acetylene is tetrahedral with a sp3 hybridization.нн H H а С—Сь H2 H-Ć-Č–H b + a H Many reactions involve a change in hybridization of one or more atoms in the starting material. In this reaction, determine the hybridization of the indicated atoms in the organic starting material, and determine if they have changed hybridization during the reaction. Atom a: Reactant: Product: Atom b: Reactant: Product:The unmistakable odor of a freshly cut cucumber is largely due to cucumber aldehyde. (a) How many sp² hybridized carbon atoms does cucumber aldehyde contain? (b) What is the hybridization of the O atom? (c) What orbitals are used to form the carbon-oxygen double bond? (d) How many o bonds does cucumber aldehyde contain? (e) How many bonds does it contain? and -gle 120° M Sp² hundre bond and I doule cucumber aldehyde H