Absorbance Compound 77 is a neutral liquid (boiling point 16I° C) containing halogen. The peak at 3.85 ppm in the 'H NMR disappeam the compound is exposed to D,O. The Mass, IR, and 'H NMR spectra, along with "C NMR data, are given below. Elemem Analysis: C, 38.52; H, 6.47; O, 17.11; contains halogen. Mass Spectrum RL-9L 100 110 120 130 140 150 10 170 180 190 OS O Infrared Spectrum Wave Number, cm -1 Wavelength, microns "H NMR ppm, 5 Structure: "C Spectral Data: triplet, 63.5 ppm; tripiet, 41.7 ppm 02000 Brooks Cole Publishing Company

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter17: Applications Of Infrared Spectrometry
Section: Chapter Questions
Problem 17.1QAP: Cyclohexnone exhibits its strongest IR absorption hand at 5.86 m, and at this wavelength there is a...
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Absorbance
Intensity
Compound 77 is a neutral liquid (boiling point 16l' C) containing halogen. The peak at 3.85 ppm in the 'H NMR disappears if
the compound is exposed to D,O. The Mass, IR, and 'H NMR spectra, along with "C NMR data, are given below. Elemental
Analysis: C, 38.52; H, 6.47; O, 17.11; contains halogen.
Compound 36 is a foul-smelling, basic liquid (boiling point 89" C). The Mass, IR, and 'H NMR spectra, along with PC NMR
data, are given below. Elemental Analysis: C, 711.22; H, 14.94; N, 13.84
Mass Spectrum
Mass Spectrun
85
85
93-95
101
90 100 110 120 130 140 150 160 170 180 190 200
09
Infrared Spectrum
Wave Number, cm
mve
Infrared Spectrum
Wave Number, om
Dosz 000e 000
0001
S00 1200 1100 1000
ode
Wavelength, microns
Wavelength, microns
'H NMR
'H NMR
ppm, 5
سستسدیبيسين
9 'udd
"C Spectral Data:
Structure:
PC Spectral Data:
Structure:
triplet, 63.5 ppm;
triplet, 44.1 ppm;
tripiet, 41.7 ppm
triplet, 48.9 ppm;
quartet, 13.7 ppn
C2000 Brooka/Cole Publiahing Company
02000 Brooks/Cole Publishing Company
Transcribed Image Text:Absorbance Intensity Compound 77 is a neutral liquid (boiling point 16l' C) containing halogen. The peak at 3.85 ppm in the 'H NMR disappears if the compound is exposed to D,O. The Mass, IR, and 'H NMR spectra, along with "C NMR data, are given below. Elemental Analysis: C, 38.52; H, 6.47; O, 17.11; contains halogen. Compound 36 is a foul-smelling, basic liquid (boiling point 89" C). The Mass, IR, and 'H NMR spectra, along with PC NMR data, are given below. Elemental Analysis: C, 711.22; H, 14.94; N, 13.84 Mass Spectrum Mass Spectrun 85 85 93-95 101 90 100 110 120 130 140 150 160 170 180 190 200 09 Infrared Spectrum Wave Number, cm mve Infrared Spectrum Wave Number, om Dosz 000e 000 0001 S00 1200 1100 1000 ode Wavelength, microns Wavelength, microns 'H NMR 'H NMR ppm, 5 سستسدیبيسين 9 'udd "C Spectral Data: Structure: PC Spectral Data: Structure: triplet, 63.5 ppm; triplet, 44.1 ppm; tripiet, 41.7 ppm triplet, 48.9 ppm; quartet, 13.7 ppn C2000 Brooka/Cole Publiahing Company 02000 Brooks/Cole Publishing Company
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