Net Volume moles of EDTA Calcium Ion Molarity (M) [4.61 Water Hardness [4.6]

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.20QAP
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4.
4.1
4.2
4.3
4.4
4.5
4.6
Quantitative determination of calcium ion concentration in water samples.
Set up a titration apparatus using a 250 mL Erlenmeyer flask with a stir bar, a 50 mL buret containing your
EDTA solution (remember to rinse your buret with a small amount of EDTA solution several times prior to
filling).
To the Erlenmeyer flask combine the following: 50 mL of distilled water, 5.0 mL of ammonia buffer, 1.0
mL of Mg-EDTA solution and 1-2 drops of Eriochrome Black T (EBT) indicator. Pipette 25.00 mL of
distilled water as a blank sample to the flask and turn on the stirrer. The solution should be a light pink
color.
Record the initial volume in the buret and titrate this solution with the EDTA solution you prepared until
the color changes from light pink to blue (Be aware that the endpoint change from one color to another will
be more subjective than a phenolphthalein acid-base endpoint). Record the final volume in the buret.
Remember that the distilled water should not contain an appreciable concentration of calcium ions so the
color should change after a very small volume of titrant has been added.
Repeat 4.2-4.3 for one of the water samples for which you determined the total dissolved solids. (Again
titrating 25.00 mL of the water sample (or other volume if desired) transferred by pipette.) Perform this
determination in duplicate trials. If the water sample has a very high calcium ion concentration you may
need to reduce the volume added in the second trial.
Repeat 4.4 for a second water sample (be sure that one of your titrations of the commercial samples is
contained on the list provided by the instructor). You should have data for 5 titrations in all: one for
distilled water and two each for two water samples (one hard and one soft).
Calculate the concentration of calcium ion in molarity for each of the titrations performed (note that 1 mole
of EDTA complexes one mole of calcium ion). Using the values below rate the water samples tested as
being soft (S), moderately hard (MH), hard (H), or very hard (VH). Note that distilled water has very little
calcium ion and the volume of the water sample added via pipette (25.00 mL or less if very hard water) is
what should be used to calculate the calcium ion molarity.
Soft (S): 0.0-6.0 x 104 M, Moderately hard (MH): 0.6-1.2 x 10-³ M,
Hard (H): 01.2-1.8 x 10-³ M, or Very hard (VH): exceeds 1.8 x 10-³ M.
Transcribed Image Text:4. 4.1 4.2 4.3 4.4 4.5 4.6 Quantitative determination of calcium ion concentration in water samples. Set up a titration apparatus using a 250 mL Erlenmeyer flask with a stir bar, a 50 mL buret containing your EDTA solution (remember to rinse your buret with a small amount of EDTA solution several times prior to filling). To the Erlenmeyer flask combine the following: 50 mL of distilled water, 5.0 mL of ammonia buffer, 1.0 mL of Mg-EDTA solution and 1-2 drops of Eriochrome Black T (EBT) indicator. Pipette 25.00 mL of distilled water as a blank sample to the flask and turn on the stirrer. The solution should be a light pink color. Record the initial volume in the buret and titrate this solution with the EDTA solution you prepared until the color changes from light pink to blue (Be aware that the endpoint change from one color to another will be more subjective than a phenolphthalein acid-base endpoint). Record the final volume in the buret. Remember that the distilled water should not contain an appreciable concentration of calcium ions so the color should change after a very small volume of titrant has been added. Repeat 4.2-4.3 for one of the water samples for which you determined the total dissolved solids. (Again titrating 25.00 mL of the water sample (or other volume if desired) transferred by pipette.) Perform this determination in duplicate trials. If the water sample has a very high calcium ion concentration you may need to reduce the volume added in the second trial. Repeat 4.4 for a second water sample (be sure that one of your titrations of the commercial samples is contained on the list provided by the instructor). You should have data for 5 titrations in all: one for distilled water and two each for two water samples (one hard and one soft). Calculate the concentration of calcium ion in molarity for each of the titrations performed (note that 1 mole of EDTA complexes one mole of calcium ion). Using the values below rate the water samples tested as being soft (S), moderately hard (MH), hard (H), or very hard (VH). Note that distilled water has very little calcium ion and the volume of the water sample added via pipette (25.00 mL or less if very hard water) is what should be used to calculate the calcium ion molarity. Soft (S): 0.0-6.0 x 104 M, Moderately hard (MH): 0.6-1.2 x 10-³ M, Hard (H): 01.2-1.8 x 10-³ M, or Very hard (VH): exceeds 1.8 x 10-³ M.
Change
3. Quantitative Determination of Calcium Ion in Water Samples by EDTA Titration
(Duplicates of two water samples, one hard and one soft as defined by the instructor.)
Sample
Trial No.
Sample
Volume
Initial
Volume
[4.3]
Final
Volume
[4.3]
Net
Volume
moles of
EDTA
Calcium Ion
Molarity (M)
[4.6]
Water
Hardness
[4.6]
Distilled Water
Pellegrino
2
25 m415 mu
2
48.
blue.
Crystal Crystal
Gerster
Z
S.
Pellegrino Geyser
3
4
15 mL 25 mL 25 ML
48,80 49.50 31,8
48 m² √2 12.75 14.4 31.8. 14.2
5
Transcribed Image Text:Change 3. Quantitative Determination of Calcium Ion in Water Samples by EDTA Titration (Duplicates of two water samples, one hard and one soft as defined by the instructor.) Sample Trial No. Sample Volume Initial Volume [4.3] Final Volume [4.3] Net Volume moles of EDTA Calcium Ion Molarity (M) [4.6] Water Hardness [4.6] Distilled Water Pellegrino 2 25 m415 mu 2 48. blue. Crystal Crystal Gerster Z S. Pellegrino Geyser 3 4 15 mL 25 mL 25 ML 48,80 49.50 31,8 48 m² √2 12.75 14.4 31.8. 14.2 5
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