The Dess–Martin reaction reacts an alcohol with the Dess–Martin periodinane. The first step displaces one of the acetate groups on the periodinane with the alcohol. A base then deprotonates one of the alpha protons, forming a new carbonyl bond, iodinane and acetic acid. The oxidation stops at this stage to give the aldehyde.Both Swern and Dess–Martin conditions will also convert a secondary alcohol to a ketone.Now apply what has just been discussed.Draw the major organic product. The Dess-Martin reaction reacts an alcohol with the Dess-Martin periodinane. The first step displaces one of the acetategroups on the periodinane with the alcohol. A base then deprotonates one of the alpha protons, forming a new carbonylbond, iodinane and acetic acid. The oxidation stops at this stage to give the aldehyde.Both Swern and Dess-Martin conditions will also convert a secondary alcohol to a ketone.Now apply what has just been discussed.OHSwern or Dess-MartinDraw the major organic product.Select Draw Rings MoreG→с H OErase2 Q

The major organic product of the given reaction is

Answered: OH Swern or Dess-Martin

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter19: Enolate Anions And Enamines

Section: Chapter Questions

Problem 19.40P: Enamines normally react with methyl iodide to give two products: one arising from alkylation at...

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The Dess–Martin reaction reacts an alcohol with the Dess–Martin periodinane. The first step displaces one of the acetate groups on the periodinane with the alcohol. A base then deprotonates one of the alpha protons, forming a new carbonyl bond, iodinane and acetic acid. The oxidation stops at this stage to give the aldehyde.

Both Swern and Dess–Martin conditions will also convert a secondary alcohol to a ketone.

Now apply what has just been discussed.

Draw the major organic product.

The Dess-Martin reaction reacts an alcohol with the Dess-Martin periodinane. The first step displaces one of the acetate
groups on the periodinane with the alcohol. A base then deprotonates one of the alpha protons, forming a new carbonyl
bond, iodinane and acetic acid. The oxidation stops at this stage to give the aldehyde.
Both Swern and Dess-Martin conditions will also convert a secondary alcohol to a ketone.
Now apply what has just been discussed.
OH
Swern or Dess-Martin
Draw the major organic product.
Select Draw Rings More
G
→
с H O
Erase
2 Q

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

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