The boiling points of several cyclic alkanes and ethers are listed in the table shown here. For small rings, there is a significant difference in boiling points between the cyclic alkane and the cyclic ether (e.g., – 76 °C vs. 10.7 °C), but for large rings, the boiling points are nearly the same (e.g., 80.7 °C vs. 88 °C). Explain. Сyclic Boiling Point (°C) Boiling Point (°C) Сyclic Alkane Ether -76 10.7 -13 50 49 66 80.7 88
The boiling points of several cyclic alkanes and ethers are listed in the table shown here. For small rings, there is a significant difference in boiling points between the cyclic alkane and the cyclic ether (e.g., – 76 °C vs. 10.7 °C), but for large rings, the boiling points are nearly the same (e.g., 80.7 °C vs. 88 °C). Explain. Сyclic Boiling Point (°C) Boiling Point (°C) Сyclic Alkane Ether -76 10.7 -13 50 49 66 80.7 88
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.21P
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