General, Organic, and Biological Chemistry - 4th edition
General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Chapter 20.5, Problem 20.7PP
Interpretation Introduction

(a)

Interpretation:

The glycosidic linkage in cellobiose should be located.

Concept Introduction:

Disaccharides are carbohydrate produced by the combination of two monosaccharides. Disaccharides are acetals. Monosaccharide contains hemiacetal. When a hemiacetal hydroxyl group is reacted with a hydroxyl group of another monosaccharide, a disaccharide is yielded.

Interpretation Introduction

(b)

Interpretation:

Carbon atoms in both rings should be numbered.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

Interpretation Introduction

(c)

Interpretation:

The glycosidic linkage should be classified as a and β and the location of the linkage should be designated using the numbers.

Concept Introduction:

If the glycosidic linkage is oriented down or below the plane of the ring then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

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Chapter 20 Solutions

General, Organic, and Biological Chemistry - 4th edition

Ch. 20.3 - Prob. 20.3PPCh. 20.3 - Prob. 20.4PPCh. 20.4 - Prob. 20.5PPCh. 20.4 - Prob. 20.6PPCh. 20.4 - Prob. 20.9PCh. 20.4 - Prob. 20.10PCh. 20.5 - Prob. 20.7PPCh. 20.5 - Prob. 20.8PPCh. 20.5 - Lactose contains both an acetal and a hemiacetal....Ch. 20.5 - Prob. 20.12PCh. 20.5 - Prob. 20.13PCh. 20.5 - Prob. 20.14PCh. 20.5 - Prob. 20.15PCh. 20.6 - Prob. 20.16PCh. 20.6 - Prob. 20.17PCh. 20.7 - Prob. 20.18PCh. 20.7 - Prob. 20.19PCh. 20.8 - Prob. 20.20PCh. 20 - Prob. 21PCh. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Prob. 24PCh. 20 - Prob. 25PCh. 20 - Prob. 26PCh. 20 - Prob. 27PCh. 20 - Prob. 28PCh. 20 - Prob. 29PCh. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Prob. 32PCh. 20 - Prob. 33PCh. 20 - Prob. 34PCh. 20 - Prob. 35PCh. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - Prob. 39PCh. 20 - Prob. 40PCh. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Prob. 43PCh. 20 - Prob. 44PCh. 20 - Prob. 45PCh. 20 - Prob. 46PCh. 20 - What product is formed when each compound is...Ch. 20 - What product is formed when each compound is...Ch. 20 - Prob. 49PCh. 20 - Prob. 50PCh. 20 - Prob. 51PCh. 20 - Prob. 52PCh. 20 - Prob. 53PCh. 20 - Prob. 54PCh. 20 - Prob. 55PCh. 20 - Prob. 56PCh. 20 - Prob. 57PCh. 20 - Prob. 58PCh. 20 - Prob. 59PCh. 20 - Prob. 60PCh. 20 - Prob. 61PCh. 20 - Prob. 62PCh. 20 - Prob. 63PCh. 20 - Prob. 64PCh. 20 - Prob. 65PCh. 20 - Prob. 66PCh. 20 - Prob. 67PCh. 20 - Prob. 68PCh. 20 - Prob. 69PCh. 20 - Prob. 70PCh. 20 - Prob. 71PCh. 20 - Prob. 72PCh. 20 - Prob. 73PCh. 20 - Prob. 74PCh. 20 - Prob. 75PCh. 20 - Prob. 76PCh. 20 - Prob. 77PCh. 20 - Prob. 78PCh. 20 - Prob. 79CPCh. 20 - Prob. 80CP
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