Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 4.4, Problem 4.14TIY
Interpretation Introduction
Interpretation:The trans-1,2-dimethylcyclohexane exists in diequatorial form and as it is an isomer of cis-1,3-dimethylcyclohexane it is expected to have sameΔG° value. Butthe measured smallerΔG° value needs to be explained.
Concept introduction:The energy difference is caused due to the difference in their conformation and interaction between different groups.
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For each of the following pairs or reactions, which is correctly labeled as having the larger equilibrium constant. There may be more than one
correct answer.
CHон рКа %3D15.5
CHCH2OH pKa =15.9
NH, pKa =9.4
CH;NH pKa =10.7
CH CH OH + NH3
CH OH + NH3
CH;CH20 + NH,"
CHO + NH, larger Kea
CH:CH,OH + CH NH2 CH,CHO + CHNH, larger Keg
CH3CH2OH + NH3 CH3CH 0 + NH
Туре: MС
QUESTION 9
CH-CH3
Name the compound. HC-CH-CH-CH-CH
CH CH2CH3
O 2-ethyl-3-propylpentane
4-ethyl-3-methylheptane
O 2,3-diethylhexane
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Determine the Kc of the following reaction:
AB4(g) + B2C(g) ⇌ AC2(g) + B2(g) Kp = 21/62500
Kc = 0.193 at 45 degrees Celsius for the reaction: Cycloheptane <--> Methylcyclohexane. What must be the initial concentration of cycloheptane for it to have an equilibrium concentration of 0.10 M?
Chapter 4 Solutions
Organic Chemistry: Structure and Function
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Prob. 4.3TIYCh. 4.2 - Prob. 4.4ECh. 4.2 - Prob. 4.6TIYCh. 4.3 - Prob. 4.7ECh. 4.4 - Prob. 4.8ECh. 4.4 - Prob. 4.10TIYCh. 4.4 - Prob. 4.11ECh. 4.4 - Prob. 4.12ECh. 4.4 - Prob. 4.14TIY
Ch. 4.6 - Prob. 4.15ECh. 4.7 - Prob. 4.16ECh. 4.7 - Prob. 4.17ECh. 4.7 - Prob. 4.18ECh. 4 - Prob. 21PCh. 4 - Prob. 22PCh. 4 - Prob. 23PCh. 4 - Prob. 24PCh. 4 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Prob. 27PCh. 4 - Prob. 28PCh. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Prob. 31PCh. 4 - Prob. 32PCh. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Prob. 38PCh. 4 - Prob. 39PCh. 4 - Prob. 40PCh. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - Prob. 43PCh. 4 - Prob. 44PCh. 4 - Prob. 45PCh. 4 - Prob. 46PCh. 4 - Prob. 47PCh. 4 - Prob. 48PCh. 4 - Prob. 49PCh. 4 - Prob. 50PCh. 4 - Prob. 51PCh. 4 - Prob. 52PCh. 4 - Prob. 53PCh. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Prob. 59PCh. 4 - Prob. 60P
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