Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Chapter 1, Problem 51EQ
The n-propyl cation can be formed from a molecule such as
When the C–Cl bond is broken so that both electrons leave with Cl, the fragments formed are
The carbon atom that had been attached to Cl is now sharing ____ electron pairs. In each shared pair the carbon atom owns ____ electron. The number of electrons that belong to carbon is ____. The formal charge on the carbon atom is ____. The correct Lewis structure for the n-propyl cation is
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Consider the resonance structures of formate.
Y-Y
>
H.
Select the true statements about the resonance structures.
Each carbon-oxygen bond is somewhere between a single and double bond.
Each oxygen atom has a double bond 50% of the time.
The actual structure of formate is an average of the two resonance forms.
The actual structure of formate switches back and forth between the two resonance forms.
Consider the resonance structures of formate.
Select the true statements about the resonance structures.
Each carbon-oxygen bond is somewhere between a single and double bond.
The actual structure of formate is an average of the two resonance forms.
Each oxygen atom has a double bond 50% of the time.
The actual structure of formate switches back and forth between the two resonance forms.
Enter a Lewis structure for each of the following ions:
1. Draw the Lewis dot structure for Al3+. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. Show the formal charge of the atom.
2. Draw the Lewis dot structure for Mg2+. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. Show the formal charge of the atom.
3. Draw the Lewis dot structure for Se2−. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. Show the formal charge of the atom.
4. Draw the Lewis dot structure for N3−N3−. Show the formal charge of the atom.
Chapter 1 Solutions
Pushing Electrons
Ch. 1 - 1. Hydrogen is a Group I element and each...Ch. 1 - Methanol has the molecular formula CH4O. Its...Ch. 1 - 3. The skeleton of chloromethane is...Ch. 1 - 4. Methanol’s skeleton is
Connecting all bonded...Ch. 1 - 5. The structure for chloromethane is
It...Ch. 1 - Prob. 6EQCh. 1 - 7. Dimethyl ether
No. of electrons in...Ch. 1 - Methylamine (CH5N) No. of electrons in structure...Ch. 1 - Methanethiol (CH4S) No. of electrons in structure...Ch. 1 - Methylal (C3H8O2) No. of electrons in structure...
Ch. 1 - Prob. 11EQCh. 1 - Adding electrons to the skeleton by making single...Ch. 1 - This is done by removing an unshared pair from...Ch. 1 - Prob. 14EQCh. 1 - Prob. 15EQCh. 1 - Prob. 16EQCh. 1 - The skeleton of acetyl chloride is . Write the...Ch. 1 - Three constitutional isomers exist for the formula...Ch. 1 - A number of constitutional isomers exist for the...Ch. 1 - Using the method outlined above, derive the...Ch. 1 - Prob. 21EQCh. 1 - Prob. 22EQCh. 1 - Prob. 23EQCh. 1 - Prob. 24EQCh. 1 - The skeleton of benzyldimethylamine is
The...Ch. 1 - The skeleton is benzaldoxime is The number of...Ch. 1 - Prob. 27EQCh. 1 - Derive Lewis structures for the compounds below....Ch. 1 - Prob. 29EQCh. 1 - Derive Lewis structures for the compounds below....Ch. 1 - Prob. 31EQCh. 1 - Derive Lewis structures for the compounds below....Ch. 1 - The Lewis structure of acetone is Circling the...Ch. 1 - Chloromethane has the Lewis...Ch. 1 - In the Lewis structure for chloromethane, the...Ch. 1 - Prob. 36EQCh. 1 - The oxygen atom in acetone possesses ____ unshared...Ch. 1 - Nitrobenzene has the skeleton
The number of...Ch. 1 - Prob. 39EQCh. 1 - Compute and add on the formal charges I these...Ch. 1 - Prob. 41EQCh. 1 - Prob. 42EQCh. 1 - Prob. 43EQCh. 1 - Prob. 44EQCh. 1 - Prob. 45EQCh. 1 - Prob. 46EQCh. 1 - Prob. 47EQCh. 1 - Compute and add on the formal charges in these...Ch. 1 - Prob. 49EQCh. 1 - Prob. 50EQCh. 1 - The n-propyl cation can be formed from a molecule...Ch. 1 - Prob. 52EQCh. 1 - Prob. 53EQCh. 1 - Methanol, CH3OH, is a compound in which the formal...Ch. 1 - When a proton becomes bonded to diethyl ether, by...Ch. 1 - Tetrahydrofuran has the structure
When a proton...Ch. 1 - Prob. 57EQCh. 1 - Prob. 58EQCh. 1 - The structure of pyridine is
When a proton...Ch. 1 - The carbon atom owns one electron from each of ...Ch. 1 - The n-butyl anion can be formed from When the CLi...Ch. 1 - The isobutyl anion can be formed from When the CNa...Ch. 1 - Prob. 63EQCh. 1 - Ethanol, , is a compound in which the formal...Ch. 1 - The loss of a proton attached to the oxygen atom...Ch. 1 - A very strong base can remove a proton from...Ch. 1 - Prob. 67EQCh. 1 - Prob. 68EQCh. 1 - Prob. 69EQCh. 1 - The homolysis of the OO bond in diacetyl peroxide...Ch. 1 - Prob. 71EQCh. 1 - Prob. 72EQCh. 1 - Prob. 73EQCh. 1 - Prob. 74EQCh. 1 - Prob. 75EQCh. 1 - Heterolytic cleavage of the CO bond to yield a...Ch. 1 - Prob. 77EQCh. 1 - Prob. 78EQCh. 1 - Prob. 79EQCh. 1 - Prob. 80EQ
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- The carbon atom owns one electron from each of shared pairs and two electrons from unshared pair. The number of electrons that belong to carbon is . Carbon is a Group element. Since the carbon atom has one more electron than it would in the neutral, unbonded state, it has a formal charge of –1 . The Lewis structure for the methyl anion is The lithium fragment must have a formal charge ofarrow_forwardIn the H2TeO4 molecule, the Te atom is the central atom.Draw a Lewis diagram of H2TeO4 for which all formal charges are equal to zero. How many double bonds are there in the structure that you have drawn?number of double bonds = ___01234Draw a Lewis diagram in which the octet rule is satisfied on all atoms. What are the formal charges on the following atoms in the structure that you have drawn? Te hydroxyl O terminal O Based on formal charge, which is the best Lewis structure for the molecule?arrow_forwardFor each molecule, or ion, write the name, then draw the Lewis structure. Next to each of these molecules, draw resonance structures, when necessary. If resonance structures exist, draw all resonance structures connected with a double arrow (+) to indicate that the actual structure is an average of the resonance structures. Give the formal charge and oxidation number of the central atom on each. 25. SCL4 30. ХeF: 31. NH,OH CO(NH2)2 33. SO2 34. CINO 26. *HCO; 27. PO,- 32. 28. 29. In exercises 27-29, be sure to try at least 35. BrOs', all possible resonance with one double bond to lower formal expanded octets charges.arrow_forward
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