Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 1.10B, Problem 1.13P

(a)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula (CH3(CH2)3CH(CH3)2).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The structure in which carbon atoms are indicated by corners and ends of lines are called “line-angle” structures. In such structures, it is understood that each carbon atom is attached to enough hydrogen atoms to give each carbon atom four bonds. The lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(b)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula ((CH3)2CHCH2Cl).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(c)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula (CH3CH2COCN).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(d)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula (CH3CHCHO).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(e)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula (CH3CHCHO).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(f)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula (CH3COCOOH).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(g)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula ((CH3CH2)2CO).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

(h)

Interpretation Introduction

To determine: The line-angle structure for the given condensed structural formula ((CH3CH2)2CO).

Interpretation: The line-angle structure for the given condensed structural formula is to be stated.

Concept introduction: The Lewis structure shows the connectivity between atoms by identifying the lone pairs of electrons in a compound. Lewis structures are also called Lewis dot structures. The valence electrons around an atom are shown by dots. Bonds between atoms are shown by lines or by a dash (-) and the lone pair of electrons is shown by a pair of dots.

Condensed formulas are those formulas which are written without showing all the individual bonds. “In condensed formulas, double or triple bonds are often drawn as they would be in a Lewis structures.”

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Chapter 1 Solutions

Organic Chemistry (9th Edition)

Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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