Concept explainers
(a)
Interpretation:
To predict the number of tin and oxide ions present in per unit cell of tin oxide.
Concept introduction:
The formula for tin oxide is
Tin oxides crystallizes in a rutile like unit cell in which
(b)
Interpretation:
Check whether it is thermodynamically feasible to transform solid
Concept introduction:
The free energy change is expressed as,
The positive value of
If the free energy change value is known then the equilibrium constant can be determined using the following equation.
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Chemistry & Chemical Reactivity
- Data are given in Appendix 1 for white phosphorus, P4(s). P4(g) has the following thermodynamic values: Hf=58.9kJ/mol , S=280.0J/kmol . What is the temperature at which white phosphorus sublimes at 1 atm pressure?arrow_forwardUse data from Appendix J to calculate the enthalpy change and the Gibbs free energy change for the reduction of chromium(III) oxide by aluminum.arrow_forwardCalcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forward
- Xenon trioxide, XeO3, is reduced to xenon in acidic solution by iodide ion. Iodide ion is oxidized to iodine, I2. Write a balanced chemical equation for the reaction.arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; ClO- is reduced to Cl-. The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, Na2S2O3; I2 is reduced to I-. The sodium thiosulfate is oxidized to sodium tetrathionate, Na2S4O6. In this analysis, potassium iodide was added in excess to 5.00 mL of bleach (d=1.00g/cm3) . If 25.00 mL of 0.0700 M Na2S2O3 was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of NaClO in the bleach?arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine, because the reaction goes to completion. The amount of iodine produced is then determined by titration with sodium thiosulfate, Na2S2O3, which is oxidized to sodium tetrathionate, Na2S4O6. Potassium iodide was added in excess to 5.00 mL of bleach (density = 1.00 g/mL). This solution, containing the iodine released in the reaction, was titrated with 0.100 M Na2S2O3. If 34.6 mL of sodium thiosulfate was required to reach the endpoint (detected by disappearance of the blue color of the starch iodine complex), what was the mass percentage of NaClO in the bleach?arrow_forward
- Using data in Appendix 1, estimate the temperature at which Fe2O3 can be reduced to iron, using hydrogen gas as a reducing agent (assume H2O(g) is the other product).arrow_forward(1) Diamond and graphite are two minerals with identical chemical compositions, pure carbon (C). Diamond is the hardest of all minerals, and graphite is one of the softest. If their compositions are identical, why do they have such profound differences in physical properties? (2) silicon and oxygen together make up nearly 75 percent by weight of the Earth's crust. But silicate minerals make up more than 95 percent of the crust. Explain the apparent discrepancy. (3) If you were given a crystal of diamond and another of quartz, how would you tell which is diamond? (4) Would you expect minerais found on the Moon, Mars, or Venus to be different from those of the Earth's crust? Explain your answer. (5) Quartz is Si02. Why does no mineral exist with the composition Si03?arrow_forward
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