(a)
Interpretation:
The product of the reaction between phenol (
Concept introduction:
In
Whether the anion behaves as a base or a nucleophile depends on the whether the substrate contains an acidic proton or an easily approachable electron-poor carbon atom. The size of the anionic species is also a factor.
(b)
Interpretation:
The product of the reaction between phenol (
Concept introduction:
In organometallic compounds, the metal-carbon bond is ionic. In most cases, the metal ion behaves as a spectator ion, and therefore, the organic part of the compound can be treated as a base or as an anionic nucleophile.
Whether the anion behaves as a base or a nucleophile depends on the whether the substrate contains an acidic proton or an easily approachable electron-poor carbon atom. The size of the anionic species is also a factor.
(c)
Interpretation:
The product of the reaction between phenol (
Concept introduction:
In organometallic compounds, the metal-carbon bond is ionic. In most cases, the metal ion behaves as a spectator ion, and therefore, the organic part of the compound can be treated as a base or as an anionic nucleophile.
Whether the anion behaves as a base or a nucleophile depends on the whether the substrate contains an acidic proton or an easily approachable electron-poor carbon atom. The size of the anionic species is also a factor.
(d)
Interpretation:
The product of the reaction between phenol (
Concept introduction:
In organometallic compounds, the metal-carbon bond is ionic. In most cases, the metal ion behaves as a spectator ion, and therefore, the organic part of the compound can be treated as a base or as an anionic nucleophile.
Whether the anion behaves as a base or a nucleophile depends on the whether the substrate contains an acidic proton or an easily approachable electron-poor carbon atom. The size of the anionic species is also a factor.
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Organic Chemistry: Principles and Mechanisms (Second Edition)
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