(a) Interpretation: The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH − is to be predicted. Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes . The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 1

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Which of (a)-(d) is not aromatic? (B) (A) (C) (D)

(a) Explain how pyrrole is isoelectronic with the cyclopentadienyl anion.(b) Specifically, what is the difference between the cyclopentadienyl anion and pyrrole?(c) Draw resonance forms to show the charge distribution on the pyrrole structure.

Answer 2

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 3

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 4

Question

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 5

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 6

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 7

Chapter 9, Problem 9.83AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with OH− is to be predicted.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason for the fact that the bicyclic material B is observed in the reaction of the trans-4-chlorocyclohexanol, but not in the reaction of the cis-4-chlorocyclohexanol is to be explained.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains the curved-arrow mechanism for reaction of cis and trans stereoisomers of 4-chlorocyclohexanol with

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