(a) Interpretation: The reason for the fact that results of given reaction is question a fundamental principle of the S N 2 reaction is to be explained. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 1

Question

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Write the reactions involved in the following reactions:(i) Clemmensen reduction(ii) Cannizzaro reaction

(b) (d) (b) The following reactions as written will NOT give the indicated product. For each of the reactions explain (a) НО (i) (ii) (iii) OH The reason why the reaction as written will not occur; How the reaction could be modified to give the indicated product (may include the use of alternative or additional reagents); What should be the outcome for the reactions as written? OH CO,CH,CH, OH 1. CH₂OH/H* 2. Zn/Hg 3. H* 1, (CH₂CH₂)CuLi 2. PCC CrO3 Pyridine 2 x CH₂MgBr H+ ỌCH3 COH(CH3)2 = OH

(c) (i) (ii) Explain what is meant by the trans effect. Using the trans effect, give a synthesis of trans-[PtCl₂(py)(PPhy)] from [PtCL]². [py = CsHsN = pyridine]

Answer 2

Question

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 3

Question

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 4

Question

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 5

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 6

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 7

Chapter 9, Problem 9.85AP

Interpretation Introduction

(a)

Interpretation:

The reason for the fact that results of given reaction is question a fundamental principle of the SN2 reaction is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The results which are obtained after the reinvestigation of the corresponding reaction are to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason for the fact that cis-P is favored in the product mixture is to be explained.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the result of the given reaction is question a fundamental principle of S_

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