Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Chapter 20.2C, Problem 20.2P
Name the following
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b) Compounds in which the –OH of the carboxyl group is replaced by certain other
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acyl halides, acid anhydrides, esters and amides. Discuss the relationship between
carboxylic acid, acid chloride and acid anhydride
Why are carbonyl compounds considered weakly acidic? Would you expect carbonyl compounds to be more acidic than alkanes? Explain.
Ränk the carboxylic acids in order of increasing acidity.
Chapter 20 Solutions
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Ch. 20.2C - Prob. 20.1PCh. 20.2C - Name the following carboxylic acids (when...Ch. 20.4B - Rank the compounds in each set in order of...Ch. 20.5 - Prob. 20.4PCh. 20.5 - Phenols are less acidic than carboxylic acids,...Ch. 20.5 - Prob. 20.6PCh. 20.7A - Prob. 20.7PCh. 20.7B - Prob. 20.8PCh. 20.7D - Draw all four resonance forms of the fragment at...Ch. 20.7D - a. Why do most long-chain fatty acids show a large...
Ch. 20.10 - Prob. 20.13PCh. 20.10 - A carboxylic acid has two oxygen atoms, each with...Ch. 20.10 - Prob. 20.15PCh. 20.10 - The mechanism of the Fischer esterification was...Ch. 20.10 - Prob. 20.17PCh. 20.12 - Show how to synthesize the following compounds,...Ch. 20.13 - Show how you would synthesize the following...Ch. 20.14 - Prob. 20.20PCh. 20.14 - Prob. 20.21PCh. 20.15 - Propose a mechanism for the reaction of benzoic...Ch. 20.15 - Prob. 20.23PCh. 20.15 - Prob. 20.24PCh. 20 - Prob. 20.25SPCh. 20 - Give both IUPAC names and common names for the...Ch. 20 - Draw the structures of the following compounds. a....Ch. 20 - Prob. 20.28SPCh. 20 - Arrange each group of compounds in order of...Ch. 20 - Predict the products (if any) of the following...Ch. 20 - Rank the following isomers in order of increasing...Ch. 20 - Prob. 20.32SPCh. 20 - What do the following pKa values tell you about...Ch. 20 - Given the structure of ascorbic acid (vitamin C):...Ch. 20 - Prob. 20.35SPCh. 20 - Show how you would accomplish the following...Ch. 20 - Predict the products and propose mechanisms for...Ch. 20 - Prob. 20.38SPCh. 20 - Prob. 20.39SPCh. 20 - Prob. 20.40SPCh. 20 - Prob. 20.44SPCh. 20 - Prob. 20.45SPCh. 20 - Predict the major form of each compound when it is...
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- Give IUPAC names for the following substances:arrow_forwardThe amines are organic weak bases which are nitrogen-containing. In the early days of organic chemistry, basic amines derived from natural sources were known as “vegetable alkali”, but they are now referred to as alkaloids. The study of alkaloids provided much of the growth of organic chemistry, phytochemistry and natural products chemistry. It remains a fascinating area of research. Please search for one naturally occurring alkaloid and provide the following: Name of the alkaloid and show its structure. Identify using arrows the polar bonds in the structure Species from where it was isolated What was the use of this alkaloid in plants (if any)? What are the pharmacological, medicinal, or environmental uses or applications of this alkaloid (if any)?arrow_forwardDescribe the acidity of different carboxylic acids and predict the products obtained when they react with strong bases.arrow_forward
- Compare and explain the acidity of phenol, ethanol, acetic acid. (Using pKa, structures of conjugate base)arrow_forwardNeed help determining the acidic and neutral components in an unknown sample. Have one of the following functional groups: Aldehyde Amine Ketone Alcohol Carboxylic acid Ester Phenol May have: Chlorine Ether Bromine Alkene lodine Alkyne Nitro Aromaticarrow_forwardWhy are carboxylic acids more acidic than phenols?arrow_forward
- Identify the functional group of each letter. Choose from: nitrile,carboxylate,carboxylic acid, eater,imine, carbonyl,methoxy,amide,phenoxy,amine, or nitroarrow_forwardEster compounds often have a sweet, pleasant odor. Many characteristic fruit scents are largely due to the natural presence of one or more ester compounds. As such, artificial scents for foods are often composed of complex mixtures of various esters. The exact identity and ratio of ingredients that compose a particular scent are closely guarded secrets in the food and fragrance industry. Suppose that you are a chemist working for a company that i creating a new line of air fresheners. The company is considering three scents: apple, pear, and pineapple. The project manager has asked you to prepare the ester compounds that are largely responsible for these scents. The structural formulas for these ester compounds are shown here: Alcohols for Air Freshener Project Molar mass Density Cost, per (g/mL) Reagent (g/mol) 1.00 L methanol 32.04 0.79 $46.20 ethanol 46.07 0.79 $112.00 1-propanol 60.10 0.80 $72.70 1-butanol 74.12 0.81 $72.60 Use the structural formulas of the alcohols and…arrow_forwardWrite balanced equations for the reaction of each of the following carboxylic acids with NaOH: formic acidarrow_forward
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