Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 3, Problem 3.11P
Explain the trends in bond angles and bond lengths of the following ions:
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(b) Arrange the following in decreasing order of bond length and bond angle with
explanation
C2H6, C2H4, C¿H2
Your assigneed ion is : AlCl4- please give a brief description that includes:
(f) actual bond angles (may use > or< symbols where appropriate).
Please note that your individual assignment may be for an ion (don't forget about charges) or a neutral atom.
Arrange the following in decreasing order of bond length and bond angle with explanation C2H6, C2H4, C2H2
Chapter 3 Solutions
Inorganic Chemistry
Ch. 3.1 - Use electron-dot diagrams and formal charges to...Ch. 3.2 - Predict the structures of the following ions....Ch. 3.2 - Prob. 3.3ECh. 3.2 - Which molecule has the smallest bond angle in each...Ch. 3.2 - Briefly account for the following observations: a....Ch. 3.2 - Does this approach work for different steric...Ch. 3 - The dimethyldithiocarbamate ion, [S2CN( CH 3 )2]-...Ch. 3 - Several resonance structures are possible for each...Ch. 3 - Draw the resonance structures for the...Ch. 3 - Three isomers having the formula N2CO are known:...
Ch. 3 - Show the possible resonance structures for nitrous...Ch. 3 - Nitric acid, which exists as HNO3 molecules in the...Ch. 3 - L. C. Allen has suggested that a more meaningful...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Explain the trends in bond angles and bond lengths...Ch. 3 - Select from each set the molecule or ¡on having...Ch. 3 - a. Compare the structures of the azide ion, N3 ,...Ch. 3 - Consider the series OCl2,O( CH3)2 , and O( SiH3)2...Ch. 3 - Two ions isoelectronic with carbon suboxide, C3O2...Ch. 3 - Explain the following: a. Ethylene, C2H4 , is a...Ch. 3 - Explain the following: a. PCI5 is a stable...Ch. 3 - X-ray crystal structures of ClOF3 and BrOF3 have...Ch. 3 - Make the following comparisons about the molecules...Ch. 3 - Prob. 3.20PCh. 3 - A solution containing the lO2F2 ion reacts slowly...Ch. 3 - The XeOF3 anion has been reported recently (D. S....Ch. 3 - Predict the structure of l(CF3)Cl2 . Do you expect...Ch. 3 - a. Which has the longer axial PF distance, PF2(...Ch. 3 - Prob. 3.25PCh. 3 - SeCl62,TeCl62 , and CIF6 are all octahedral, but...Ch. 3 - Prob. 3.27PCh. 3 - The thiazyldichloride ion, NSCl2- , is...Ch. 3 - Sketch the most likely structure of PCl3Br2 and...Ch. 3 - a. Are the CF3 groups in PCl3( CF3)2 more likely...Ch. 3 - Of the molecules C1SO2CH3,C1SO2CF3 , and ClSO2CCl3...Ch. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Although the CF distances and the FCF bond angles...Ch. 3 - The Cl...Cl distance in CCl4 is 289 pm, and the...Ch. 3 - The FCF angle in F2CO , shown here, is 109.5°; the...Ch. 3 - Compounds in which hydrogen is the outer atom can...Ch. 3 - For each of the following bonds, indicate which...Ch. 3 - Give Lewis dot structures and shapes for the...Ch. 3 - Give Lewis dot structures and sketch the shapes...Ch. 3 - Which of the molecules in Problem 3.41 are polar?Ch. 3 - Which of the molecules in Problem 3.42 are polar?Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46P
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- In each of the following molecules, a central atom is surrounded by a total of three atoms or unshared electron pairs: SnCl2, BCl3, SO2. In which of these molecules would you expect the bond angle to be less than 120? Explain your reasoning.arrow_forwardWhat are the relationships among bond order, bond energy, and bond length? Which of these quantities can be measured?arrow_forward• identify sigma and pi bonds in a molecule and explain the difference between them.arrow_forward
- What would you expect to be the electron-group arrangement around atom A in each of the following cases? For each arrangement, give the ideal bond angle and the direction of any expected deviation:arrow_forwardWhat role does electronegativity plays in rationalizing bond angles?arrow_forwardThe VSEPR model was developed before any xenon com-pounds had been prepared. Thus, these compounds provided anexcellent test of the model’s predictive power. What would youhave predicted for the shapes of XeF₂, XeF₄, and XeF₆?arrow_forward
- What would you expect to be the electron-group arrangement around atom A in the following case? Give the ideal bond angle. Y X A- -X Electron-group arrangement: trigonal planar trigonal bipyramidal square planar Ideal bond angle:arrow_forwardConsider the Lewis Structure for the molecule, SeF4. On your own, make a sketch of the VSEPR shape, and use that to answer the following questions: :F: F-Se-F: :F: Part A What is the electronic geometry of this molecule? O trigonal bipyramidal O t-shaped O trigonal pyramidal O tetrahedral O square planar see-saw O octahedral O O Oarrow_forwardUsing hybridization and the long method for determining the Lewis Structures, show the most feasible representation of the following compounds: AsCl4+ OClF4- (Cl is the central atom) O3BrF (Br is the central atom)arrow_forward
- What is the possible identity of X for a molecule XCl3- with a molecular geometry of trigonal pyramidal?arrow_forwardWhich theory have been given to explain shapes of the molecules. On the basis of its various postulates explain: (i) From the given examples of SF4, BF4', XeF4, IC14', the number of species having two lone pairs of electrons (ii) The bond distances and angles in SO2C12 and S2C12arrow_forwardEstimate the percent ionic character of the bond in each of the following species. All the species are unstable or reac- tive under ordinary laboratory conditions, but they can be observed in interstellar space. Bond Length (À) Dipole Moment (D) OH 0.980 1.66 CH 1.131 1.46 CN 1.175 1.45 1.246arrow_forward
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