Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 3, Problem 3.28P
The thiazyldichloride ion,
a. Which of these species has the smaller
b. Which do you predict to have the longer
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The following will exhibit ionization
isomerism, EXCEPT:
A. Pt(NH3)2CI2
B. Pt(NH3),Cl,Br2
C. Pt(en);(ox)Cl2
D. Pt(H,O)2(NH3)2CI2
Use the following data to estimate AH; for potassium bromide.
K(s) +
Br2 (9) - KBr(a)
Lattice energy
-671 kJ/mol
Ionization energy for K
419 kJ/mol
Electron affinity of Br
-325 kJ/mol
Bond energy of Br2
Enthalpy of sublimation for K
193 kJ/mol
90. kJ/mol
AH =
kJ/mol
5. Explain why lattice enthalpy calculations based on the Bom-Mayer equation
reproduce the experimentally detemined values to 99% for LICI but only 91%
for AgCl?
Chapter 3 Solutions
Inorganic Chemistry
Ch. 3.1 - Use electron-dot diagrams and formal charges to...Ch. 3.2 - Predict the structures of the following ions....Ch. 3.2 - Prob. 3.3ECh. 3.2 - Which molecule has the smallest bond angle in each...Ch. 3.2 - Briefly account for the following observations: a....Ch. 3.2 - Does this approach work for different steric...Ch. 3 - The dimethyldithiocarbamate ion, [S2CN( CH 3 )2]-...Ch. 3 - Several resonance structures are possible for each...Ch. 3 - Draw the resonance structures for the...Ch. 3 - Three isomers having the formula N2CO are known:...
Ch. 3 - Show the possible resonance structures for nitrous...Ch. 3 - Nitric acid, which exists as HNO3 molecules in the...Ch. 3 - L. C. Allen has suggested that a more meaningful...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Explain the trends in bond angles and bond lengths...Ch. 3 - Select from each set the molecule or ¡on having...Ch. 3 - a. Compare the structures of the azide ion, N3 ,...Ch. 3 - Consider the series OCl2,O( CH3)2 , and O( SiH3)2...Ch. 3 - Two ions isoelectronic with carbon suboxide, C3O2...Ch. 3 - Explain the following: a. Ethylene, C2H4 , is a...Ch. 3 - Explain the following: a. PCI5 is a stable...Ch. 3 - X-ray crystal structures of ClOF3 and BrOF3 have...Ch. 3 - Make the following comparisons about the molecules...Ch. 3 - Prob. 3.20PCh. 3 - A solution containing the lO2F2 ion reacts slowly...Ch. 3 - The XeOF3 anion has been reported recently (D. S....Ch. 3 - Predict the structure of l(CF3)Cl2 . Do you expect...Ch. 3 - a. Which has the longer axial PF distance, PF2(...Ch. 3 - Prob. 3.25PCh. 3 - SeCl62,TeCl62 , and CIF6 are all octahedral, but...Ch. 3 - Prob. 3.27PCh. 3 - The thiazyldichloride ion, NSCl2- , is...Ch. 3 - Sketch the most likely structure of PCl3Br2 and...Ch. 3 - a. Are the CF3 groups in PCl3( CF3)2 more likely...Ch. 3 - Of the molecules C1SO2CH3,C1SO2CF3 , and ClSO2CCl3...Ch. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Although the CF distances and the FCF bond angles...Ch. 3 - The Cl...Cl distance in CCl4 is 289 pm, and the...Ch. 3 - The FCF angle in F2CO , shown here, is 109.5°; the...Ch. 3 - Compounds in which hydrogen is the outer atom can...Ch. 3 - For each of the following bonds, indicate which...Ch. 3 - Give Lewis dot structures and shapes for the...Ch. 3 - Give Lewis dot structures and sketch the shapes...Ch. 3 - Which of the molecules in Problem 3.41 are polar?Ch. 3 - Which of the molecules in Problem 3.42 are polar?Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The noble gas electron configuration of the ion P2 is And the Lewis structure of this ion is Is this ion is paramagnetic or diamagnetic? Paragraph в I + v ... Lato (Recom... V 19рх... -123 lilıarrow_forward1. Which is the most thermodynamically stable state of I? a. H5IO6b.I- c. I2 d.HIO 2. Which species will tend to disproportionate? a.H5IO6 b.HIO c. I2 d. I-arrow_forward* OWLV2 | Online teachin X C According To The Following + akeAssignment/takeCovalentActivity.do?locator-assignment-take&takeAssignmentSessionLocator= [Review Topics] [References] Use the References to access important values if needed for this qu The illustration to the left represents a mixture of nitrogen ( blue ) and oxygen ( red ) molecules. tarted If the molecules in the above illustration react to form N2O4 according to the equation N2 2 O2 N2O4. the limiting reagent is the number of N,0, molecules formed is and the number of molecules in excess is SuhwitApayn a more group attempts remaining a $arrow_forward
- b) Answer the following question and give a brief explanation for your answers. a. Which one is more reactive : cesium, Cs or potassium, K? Explain b. Which one is more electronegative silicon, Si or tellurium, Te? Explain c. Arrange the following according to their size : smallest to largest. Justify your answer. O2 , F, Nearrow_forwardDescribe the bonding in H2S, CH4, H2CO and HCN using the localized electron model.arrow_forwardThe percent ionic character of the bonds in several interhalogen Molecules (as estimated from their measured dipole moments and bond lengths) are ClF (11%), BrF(15%), BrCl (5.6%), ICl(5.8%), and IBr (10%). Estimate the percent ionic characters for each of these molecules, using the equation in Problem 37, and compare them with the given values.arrow_forward
- Give the Lewis structure, molecular structure, and hybridization of the oxygen atom for OF2. Would you expect OF2 to be a strong oxidizing agent like O2F2 discussed in Exercise 61?arrow_forwardAlthough nitrogen trifluoride (NF3) is a thermally stable compound, nitrogen triiodide (Nl3) is known to be a highly explosive material. NI3 can be synthesized according to the equation BN(s)+3IF(g)BF3(g)+NI3(g) a. What is the enthalpy of formation for NI3(s) given the enthalpy of reaction ( 307 kJ) and the enthalpies of formation for BN(s) (254 kJ/mol), IF(g) ( 96 kJ/mol), and BF3(g) ( 1136 kJ/mol)? b. It is reported that when the synthesis of NI3 is conducted using 4 moles of IF for every l mole of BN. one of the by-products isolated is [IF2]+ [BF4]. What are the molecular geometries of the species in this by-product? What are the hybridizations of the central atoms in each species in the by-product?arrow_forwardWhich one of the following species is paramagnetic? (Consider the necessary molecular orbitals) Li Be "Lanthanide series57" ** Actinide series Select one: O a. H2 O b. N Oc O2 O d. F2 品 に8Y ”山 あ非arrow_forward
- The percent ionic character of a bond between elements A and B may be approximated by the expression %IN = 100[1 - e^(-1/4(XA - XB))], where XA and XB are the electronegavities for the respective elements. What is the the percent ionic character of the interatomic bonds for Fe2O3? What type of bonding would you expect in Fe2O3? Note: Use 1.8 for the electronegativity for Fe and 3.5 for the electronegativity for O.arrow_forwardWhich of the following elements will have the largest first ionization energy?A. CB. ClC. NaD. F I dont understand this.arrow_forwardBond dissociation energy of F2 is less than that of Cl2 . Why?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY