Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Question
Chapter 19, Problem 19.43P
Interpretation Introduction
Interpretation:
N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and
Concept Introduction:
Amides are formed by a reaction with a
The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:
The hydrolysis of amide so formed can give back the carboxylic acid and amine.
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Using the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.
Explain why
CH3 CH2 CH2NH2
is a Brønsted
base.
Its water
solutions
are basic.
All
substances
containing
nitrogen
atoms are
Brønsted
bases.
This
amine is a
proton
donor.
This
amine can
ассеpt a
proton
from a
proton
donor.
Determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products:(a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.
Chapter 19 Solutions
Introduction to General, Organic and Biochemistry
Ch. 19.1 - Prob. 19.1PCh. 19.4 - Problem 19-2 Complete the equation for each...Ch. 19.4 - Prob. 19.3PCh. 19 - Prob. 19.4PCh. 19 - Write the IUPAC name for each compound.Ch. 19 - Prob. 19.6PCh. 19 - Prob. 19.7PCh. 19 - Prob. 19.8PCh. 19 - Prob. 19.9PCh. 19 - 0 Complete the equations for these reactions.
Ch. 19 - Prob. 19.11PCh. 19 - Prob. 19.12PCh. 19 - Prob. 19.13PCh. 19 - Prob. 19.14PCh. 19 - Prob. 19.15PCh. 19 - 6 Why are Dacron and Mylar referred to as...Ch. 19 - 7 What type of structural feature do the...Ch. 19 - Prob. 19.18PCh. 19 - Prob. 19.19PCh. 19 - 0 Show how triphosphoric acid can form from three...Ch. 19 - 1 Write an equation for the hydrolysis of...Ch. 19 - 2 (Chemical Connections 19A) Locate the ester...Ch. 19 - Prob. 19.23PCh. 19 - Prob. 19.24PCh. 19 - Prob. 19.25PCh. 19 - Prob. 19.26PCh. 19 - Prob. 19.27PCh. 19 - 8 (Chemical Connections 19C) Once it has been...Ch. 19 - Prob. 19.29PCh. 19 - Prob. 19.30PCh. 19 - Prob. 19.31PCh. 19 - Prob. 19.32PCh. 19 - Prob. 19.33PCh. 19 - 4 (Chemical Connections 19F) Why do Lactomer...Ch. 19 - Prob. 19.35PCh. 19 - Prob. 19.36PCh. 19 - Prob. 19.37PCh. 19 - 8 In Chapter 22, we will discuss a class of...Ch. 19 - Prob. 19.39PCh. 19 - Prob. 19.40PCh. 19 - Prob. 19.41PCh. 19 - Prob. 19.42PCh. 19 - Prob. 19.43PCh. 19 - Prob. 19.44PCh. 19 - Prob. 19.45PCh. 19 - Prob. 19.46PCh. 19 - Prob. 19.47PCh. 19 - Prob. 19.48PCh. 19 - Prob. 19.49P
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