The expected products of the given acid catalysed reaction are to be stated. Concept introduction: When aldehydes or ketones react with a primary amine , formation of a carbinolamine takes place. Then, dehydration takes place to give C = N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

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The reaction of a nitrile with an alcohol in the presence of a strong acid forms an N-substituted amide. This reaction, known as the Ritter reaction, doesnot work with primary alcohols. a. Why does the Ritter reaction not work with primary alcohols? b. Provide an explanation for why an amide is less susceptible to nucleophilic attack than its corresponding ester.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

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Answer 5

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

Answer 6

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

Answer 7

Chapter 22.4, Problem 22.8P

(a)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a primary amine, formation of a carbinolamine takes place. Then, dehydration takes place to give C=N double bond of an imine. Imine formation takes place in the presence of an acid or a base. This reaction is reversible and it is accompanied by loss of water molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The expected products of the given acid catalysed reaction are to be stated.

Concept introduction:

When aldehydes or ketones react with a secondary amine, formation of enamine takes place. The nitrogen analog of an enol is known as enamine. From the resonating structures of enamine, it is clear that it nucleophilic in nature.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.2A - Prob. 22.2P Ch. 22.4 - Without looking back, propose a mechanism for the...Ch. 22.4 - Prob. 22.8P Ch. 22.4 - Prob. 22.9P Ch. 22.5A - Prob. 22.10P Ch. 22.5A - Prob. 22.11P Ch. 22.5B - Prob. 22.12P Ch. 22.5B - Predict the products of the following reactions....Ch. 22.5B - Which compounds will give positive iodoform tests?...Ch. 22.5C - Propose a mechanism for the acid-catalyzed...

Solution Summary: The author explains the expected products of the given acid catalysed reaction.

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