Physics for Scientists and Engineers
6th Edition
ISBN: 9781429281843
Author: Tipler
Publisher: MAC HIGHER
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Chapter 37, Problem 22P
To determine
The separation distance of 2 nitrogen atoms.
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The characteristic rotational energy for a diatomic molecule consisting of two idential atoms of mass 14 u (unified mass units) is 3.68 e-4 eV. Calculate the separation distance between the two atoms.
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In solid KCI the smallest distance between the centers of a. potassium ion and a chloride ion is 314 pm. Calculate the length of the edge of the unit cell and the density of KCI, assuming it has the same structure as sodium chloride.
N 2 has a molecular weight of 28.02 g/mol a bit larger than that of a Ne atom, 20.18 g/mol.
(a) At a particular temperature, Z trans= 1.90 x 10 26 for Ne in a specific container. What is the translational partition function for a N2 molecule in this container at the same temperature?
(b) At 100 K, the rotational partition function for N2is found to be 17.39. What would you expect it to be at 500 K?
Chapter 37 Solutions
Physics for Scientists and Engineers
Ch. 37 - Prob. 1PCh. 37 - Prob. 2PCh. 37 - Prob. 3PCh. 37 - Prob. 4PCh. 37 - Prob. 5PCh. 37 - Prob. 6PCh. 37 - Prob. 7PCh. 37 - Prob. 8PCh. 37 - Prob. 9PCh. 37 - Prob. 10P
Ch. 37 - Prob. 11PCh. 37 - Prob. 12PCh. 37 - Prob. 13PCh. 37 - Prob. 14PCh. 37 - Prob. 15PCh. 37 - Prob. 16PCh. 37 - Prob. 17PCh. 37 - Prob. 18PCh. 37 - Prob. 19PCh. 37 - Prob. 20PCh. 37 - Prob. 21PCh. 37 - Prob. 22PCh. 37 - Prob. 23PCh. 37 - Prob. 24PCh. 37 - Prob. 25PCh. 37 - Prob. 26PCh. 37 - Prob. 27PCh. 37 - Prob. 28PCh. 37 - Prob. 29PCh. 37 - Prob. 30PCh. 37 - Prob. 31PCh. 37 - Prob. 32PCh. 37 - Prob. 33PCh. 37 - Prob. 34PCh. 37 - Prob. 35PCh. 37 - Prob. 36PCh. 37 - Prob. 37PCh. 37 - Prob. 38PCh. 37 - Prob. 39PCh. 37 - Prob. 40PCh. 37 - Prob. 41PCh. 37 - Prob. 42PCh. 37 - Prob. 43P
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- The bond length in F2 is 1.417 Å, instead of twice theatomic radius of F, which is 1.28 Å. What can account forthe unexpected length of the F_ F bond?arrow_forwardA CO molecule starts in the vibrational and rotational ground state with k = 900 N/m. Calculate the energy of the CO molecule.arrow_forwardFor an O2 molecule, the constant E is approximately 0.00018 eV. Estimate the rotational partition function for an O2 molecule at room temperature.arrow_forward
- To determine the equilibrium separation of the atoms in the HCl molecule, you measure the rotational spectrum of HCl. You find that the spectrum contains these wavelengths (among others): 60.4 mm, 69.0 mm, 80.4 mm, 96.4 mm, and 120.4 mm. (a) Use your measured wavelengths to find the moment of inertia of the HCl molecule about an axis through the center of mass and perpendicular to the line joining the two nuclei. (b) The value of l changes by +-1 in rotational transitions. What value of l for the upper level of the transition gives rise to each of these wavelengths? (c) Use your result of part (a) to calculate the equilibrium separation of the atoms in the HCl molecule. The mass of a chlorine atom is 5.81 * 10-26 kg, and the mass of a hydrogen atom is 1.67 * 10-27 kg. (d) What is the longest-wavelength line in the rotational spectrum of HCl?arrow_forwardThe bond length in the BrF molecule is 178 pm and the measured dipole moment is 1.29 D (debyes). What is the magnitude of the negative charge (in units of the electronic charge e) on F in BrF? (1 debye = 3.34 × 10−30 coulomb-meters; electronic charge = e = 1.6 × 10−19 coulombs). A. 0.15 B. 0.24 C. 0.33 D. 1.00 E. 1.6 × 10−19arrow_forwardWhat is the energy of a photon emitted from a CO molecule that transitions from the rotational Ji to Ji-1 level. Express your answer in units of ℏ^2/I, so you just have an integer value as a final answer. Values: Ji = 3 The equation I have in the teacher's ppt is E_rotational = (J*(J+1)*ℏ^2)/(2*I)arrow_forward
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