Physics for Scientists and Engineers
6th Edition
ISBN: 9781429281843
Author: Tipler
Publisher: MAC HIGHER
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 37, Problem 39P
To determine
The expression for equilibrium separation.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. Find, in terms of A and B, (a) the value r0 at which the energy is a minimum and (b) the energy E required to break up a diatomic molecule.
The potential energy of two atoms in a diatomic molecule is approximated by U(r) = a/r12-b/r6, where r is the spacing between atoms and a and b are positive constants.
Suppose the distance between the two atoms is equal to the equilibrium distance found in part A. What minimum energy must be added to the molecule to dissociate it -
that is, to separate the two atoms to an infinite distance apart? This is called the dissociation energy of the molecule. Express your answer in terms of the variables a and b.
For the molecule CO, the equilibrium distance between the carbon and oxygen atoms is 1.13\times 10-10m and the dissociation energy is 1.54\times 10-18J per
molecule. Find the value of the constant a. Express your answer in joules times meter in the twelth power. Find the value of the constant b. Express your answer in joules
times meter in the sixth power.
Consider two immiscible liquids such as water and oil. If a spherical oil molecule of radius r is taken out of the oil phase and placed in the water phase, the unfavorable energy of this transfer is proportional to the area of the solute (oil) molecule newly exposed to the solvent (water) multiplied by the interfacial energy, i, of the oil-water interface. The interfacial energy of the bulk cyclohexane-water interface is i = 50 mJ m-2, and the radius of a cyclohexane molecule is 0.28 nm. Using Boltzmann distribution, estimate the solubility of cyclohexane in water at 25 C in units of mol L-1.The concentration of water in water phase is 55.5 mol L-1.
Chapter 37 Solutions
Physics for Scientists and Engineers
Ch. 37 - Prob. 1PCh. 37 - Prob. 2PCh. 37 - Prob. 3PCh. 37 - Prob. 4PCh. 37 - Prob. 5PCh. 37 - Prob. 6PCh. 37 - Prob. 7PCh. 37 - Prob. 8PCh. 37 - Prob. 9PCh. 37 - Prob. 10P
Ch. 37 - Prob. 11PCh. 37 - Prob. 12PCh. 37 - Prob. 13PCh. 37 - Prob. 14PCh. 37 - Prob. 15PCh. 37 - Prob. 16PCh. 37 - Prob. 17PCh. 37 - Prob. 18PCh. 37 - Prob. 19PCh. 37 - Prob. 20PCh. 37 - Prob. 21PCh. 37 - Prob. 22PCh. 37 - Prob. 23PCh. 37 - Prob. 24PCh. 37 - Prob. 25PCh. 37 - Prob. 26PCh. 37 - Prob. 27PCh. 37 - Prob. 28PCh. 37 - Prob. 29PCh. 37 - Prob. 30PCh. 37 - Prob. 31PCh. 37 - Prob. 32PCh. 37 - Prob. 33PCh. 37 - Prob. 34PCh. 37 - Prob. 35PCh. 37 - Prob. 36PCh. 37 - Prob. 37PCh. 37 - Prob. 38PCh. 37 - Prob. 39PCh. 37 - Prob. 40PCh. 37 - Prob. 41PCh. 37 - Prob. 42PCh. 37 - Prob. 43P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Similar questions
- define the chemical potential in terms of derivatives of the ĈE energy E and enthalpy H. For a one component system, these are u= ON and Evaluate these expressions for an ideal gas and compare to ON µ = -kT In (kT/PA³ ) from H=| P,s OF and |= 1 TP ON v.rarrow_forwardConsider the Lennard-Jones potential between atoms of mass m in a solid material. a) Find the dependence of the equilibrium position r0 on the parameters in the potential. b).For small perturbations, δr around r0, determine the restoring force as a function of δr and as a result determine the natural frequency ω0 of oscillation of the atoms as a function of the coefficients in the Lennard-Jones potential.arrow_forwardQs: Find the limit for the following functions: - Vx-2 1- lim x→4 x-4 (2x-3)(Vx-1) 2- lim x-1 2x2+х-3arrow_forward
- Glasses are materials that are disordered – and not crystalline – at low temperatures. Here is a simple model. Consider a system with energy E, the number of accessible microstates is given by a Gaussian function: Ω(E) = Ω0 e −(E−E¯) 2/(2∆2 ) , where Ω0 and E¯ and ∆ are positive constants. E¯ is the average energy. In this problem, we consider only the states whose energy E is below E¯. 1. Show that the entropy is an inverted parabola: S(E) = S0 − α (E − E¯) Find S0 and α. Write your answers in terms Ω0, ∆, and other universal constants. 2. An entropy catastrophy happens when S = 0, which occurs at energy E0. (i) Find E0. (ii) What is the number of accessible states for energy below E0? 3. The glass transition temperature Tg is the temperature of entropy catastrophy. Compute Tg. 4. Find the energy E as a function of T. 5. Without any calculation, explain why E → E¯ as T → +∞. Hint: consider the Boltzmann distributionarrow_forwardQuestion 2: Suppose a solid contains 3 identical independent one dimensional oscillstors and sar i.e. 0, 1 and 2, then- he only the ee td mer O there is only one macrostate with total energy zero. o there are two macrostates with total energy zero. O There are nine macrostates with total energy zero. O There are three macrostates with total energy zero.arrow_forwardOne description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.arrow_forward
- Q/A particle of mass m moves in one dimension according to the potential energies . (a) V(æ)= a² + %3D (b) V(x) = kxe-bz (c) V (x) = k(xª – b²x²) %3D Find the equilibrium position for each state and test its stability?arrow_forward(a): Calculate Miller's indices in the hexagonal structure of its intersections. ai = 1, ar--1/2, as = 1,c= o and draw it. (b): the potential energy of a diatomic molecule is given by U = A B . where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV. m2 and B = 1.488 x 10 eV.m. Find the separation distance at which the energy of the molecule is a minimum. Q3: Calculate the dhai of tetragonal using the concepts of reciprocal latticearrow_forwardQ3: The potential energy function for the force between two atoms in a diatomic molecule is approximately given by U(x) = - 읆 옮 , where a and b are constant and x is the distance between the atoms. If the dissociation energy of the molecule is (U(x= ∞) -U at equilibrium), D is (a) b²/6a (b) b²/2a (c) b²/12a (d) b²/4aarrow_forward
- One model for the potential energy of a two-atom molecule, where the atoms are separated by a distance r, is U(r) = Uo[(¹) ¹2 – ( )²] where ro = 0.8 nm and U₁ = 6.1 eV. Note: 1 eV = 1.6 × 10-19 J. Some helpful units: [Force] = eV/nm [Energy] = eV [distance] = nm Equilibrium Distance What is the distance between the atoms when the molecule is in stable equilibrium? Click here for a hint T'eq Hint: Hint: Hint: Hint: Hint: Hint: Force If the distance between the atoms increases from equilibrium by r₁ = 0.35 nm, then what is the force from one atom on the other associated with this potential energy? (Enter your answer as postive if they repel each other, and negative if they attract.) Fr(req+r₁) Hint: Hint: 0.89105934nm Kinetic Energy Hint: The atoms are oscillating back and forth. The maximum separation of the atoms is r₂ = 2 nm. What is the kinetic energy of the atoms when they are separated by the equilibrium distance? Click here for a hint K(req) Hint: Hint: = -1.288eV/nm 3.99eVarrow_forwardas a child, we were taught about molecules and atoms and how they work. now we are grown up and taught more in detail this time. let's say we have a ΑΒ U (r)=- 12 r r diatOmic molecule with (potential energy) A~> THIS IS A + CONSTANT ~> THIS IS A + CONSTANT r~> separation between da at0ms :( В dis potential is due to our force dat will compact all da atoms togetha FIND: a) pls get the equil1brium seperation (da distance betwe3n da atomz) b) pls also tell me if da force between them atoms are good or no if r is bigger than what (a) is. c) pls also tell me if da force between them atoms are good(attraction) or no (revulsion) if r is smaller than what (a) is. thank you so much. please help. i really need itarrow_forwardOne model for the potential energy of a two-atom molecule, where the atoms are separated by a distance r, is U(r) = U₁[(¹)¹² – ()] where ro = 0.8 nm and ₹₁ = 6.1 eV. 19 Note: 1 eV = 1.6 × 10-¹⁹ J. Some helpful units: [Force] = eV/nm [Energy] = eV [distance] = nm Equilibrium Distance What is the distance between the atoms when the molecule is in stable equilibrium? Click here for a hint req Hint: Hint: Hint: Hint: Hint: Force If the distance between the atoms increases from equilibrium by r₁ = 0.35 nm, then what is the force from one atom on the other associated with this potential energy? (Enter your answer as postive if they repel each other, and negative if they attract.) Fr(req+r₁) Hint: 0.89105934nm Hint:arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage Learning
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning