Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 7, Problem 7.28P
Interpretation Introduction

Interpretation:

The possible stereoisomeric products formed by the bromine addition to cyclohexene are to be stated.

Concept introduction:

When two molecules consist of the same atoms which are linked in the same sequence, but the atoms are placed differently in space, then they are called the stereoisomers.

The organic compounds that are found to be non-superimposable on their mirror images are called as enantiomers. Enantiomer of a compound has opposite configuration.

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(a) What monobromo allylic substitution products would result from reaction of each of PRACTICE P the following compounds with NBS in the presence of peroxides and/or light? (b) In the case of isomeric products for any reaction, which would you predict to be the most stable based on the double bond in the product? (c) Draw the resonance hybrid(s) for the allylic radical that would be involved in each reaction. (i) (ii) V dil.... (iii) oily
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