(a) Interpretation: Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted. Concept introduction: The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds. There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 1

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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(b) (c) Draw the more stable chair conformation of each of the following compounds in which an sp³-hybridized heteroatom is part of the ring. ZI

(a) All Isomers have the same molecular formulae. Explain this further. Hint what does it mean to have the same molecular formulae? (b) What is Constitutional (structural) isomerism? Hint, isomers are different, so what is different between a pair of constitutional isomers (see the chart on the last page for examples). (c) What is Conformational isomerism?

5) relationship between the pairs of structures. NOTE: Each term may be used more than Choose the term from the five terms listed below that BEST describes the once and not all terms need be used. Identical Diastereomers Enantiomers Constitutional isomers Not isomers CH3 CH3 ÇI H3C-Br CH3 Br -CI H,C. D-H H3C- Br H- -D Br CH3 -CI ČH3 OH H3C, CHO OHC, OH OH H. HO CHO OHC CH3 H. OH ÓH

Answer 2

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 3

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 4

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 5

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 6

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 7

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the saturated six-membered ring compounds are expressed and explained in the chair conformations.

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