Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 24, Problem 24.22P
Interpretation Introduction

(a)

Interpretation:

The Fisher projection for the aldaric acid and the structure of 1, 4-lactone which is derived from the oxidation of D-galactose is to be draw.

Concept introduction:

Fischer projections is a two dimensional representation of organic compounds. It was proposed to represent glucose molecules. The carbon chain is represented vertically; the hydoxy groups and hydrogen atoms are represented horizontally, according to their stereochemistry.

Interpretation Introduction

(b)

Interpretation:

The Fisher projection for the aldaric acid and the structure of 1, 4-lactone which is derived from the oxidation of D-mannose is to be draw.

Concept introduction:

Fischer projections is a two dimensional representation of organic compounds. It was proposed to represent glucose molecules. The carbon chain is represented vertically; the hydoxy groups and hydrogen atoms are represented horizontally, according to their stereochemistry.

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Arabinoxylan is a copolymer of arabinose and xylose-two five-carbon sugars. A portion of the polysaccharide is shown here. (a) Identify and classify each glycosidic linkage. (b) Based on the structure, do you think arabinoxylan functions as a storage polysaccharide or a structural polysaccharide? Explain your reasoning. HOH,C. OH Но OH OH но но OH Но LO. Но HOH,C HOH2C НО OH OH CH,OH
Draw the structure of: (a) a polysaccharide formed by joining D-mannose units in 1→4-β- glycosidic linkages; (b) a polysaccharide formed by joining D-glucose units in 1→6-α- glycosidic linkages. The polysaccharide in (b) is dextran, a component of dental plaque.
Which statement about saccharides is correct? (A). Alpha anomers are more common than beta anoomers. (B). Two monosaccharides can form a disaccharide and oxygen. (C). Polysaccharides with alpha or beta glycosidic linkages have the different properties. (D). Disaccharides can be cyclic or acyclic.
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