The matching of compounds A , B , C and D with their correct name on the basis of experimental facts is to be stated. Concept introduction: The periodic acid acts as a strong oxidizing agent. The periodic acid reacts with a vicinal diol to form two aldehyde after breaking the carbon-carbon bond between the vicinal diol. The gem diol does not react with periodic acid as vicinal diol reacts.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.59AP

Interpretation Introduction

Interpretation:

The matching of compounds A, B, C and D with their correct name on the basis of experimental facts is to be stated.

Concept introduction:

The periodic acid acts as a strong oxidizing agent. The periodic acid reacts with a vicinal diol to form two aldehyde after breaking the carbon-carbon bond between the vicinal diol. The gem diol does not react with periodic acid as vicinal diol reacts.

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The reaction of 3,4-dimethyl-3-hexanol (3,4-dimethylhexan-3-ol) with HBr generates compound A as the major product. Treatment of compound A with a strong base gives two isomers of compound B as the major product, along with one isomer of compound C and one isomer of compound D as minor products, all of which have one double-bond equivalent. Identify compounds A, B, C, and D and give their names. By what mechanism does the reaction of 3,4-dimethyl-3-hexanol with HBr occur? By what mechanism does the reaction of A with strong base to form B occur? Propose reaction conditions for an alternative, one-step method for converting 3,4-dimethyl-3-hexanol directly to compound B.

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.59AP

Interpretation Introduction

Interpretation:

The matching of compounds A, B, C and D with their correct name on the basis of experimental facts is to be stated.

Concept introduction:

The periodic acid acts as a strong oxidizing agent. The periodic acid reacts with a vicinal diol to form two aldehyde after breaking the carbon-carbon bond between the vicinal diol. The gem diol does not react with periodic acid as vicinal diol reacts.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.59AP

Interpretation Introduction

Interpretation:

The matching of compounds A, B, C and D with their correct name on the basis of experimental facts is to be stated.

Concept introduction:

The periodic acid acts as a strong oxidizing agent. The periodic acid reacts with a vicinal diol to form two aldehyde after breaking the carbon-carbon bond between the vicinal diol. The gem diol does not react with periodic acid as vicinal diol reacts.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11, Problem 11.59AP

Interpretation Introduction