a) Interpretation: The more reactive nucleophile among the following pairs (CH 3 ) 2 N - or (CH 3 ) 2 NH Concept introduction: The major factor which affects the S N 2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Question

Which of the following species is likely to be a nucleophile and which an electrophile? (a) CH3CI {b) CH3S (c) N CH3 {d) N. CH3CH

Answer 1

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Which of the following species is likely to be a nucleophile and which an electrophile? (a) CH3CI {b) CH3S (c) N CH3 {d) N. CH3CH

For each of the following pairs of species, which is the stronger nucleophile in ethanol? Explain. (a) H3C-OH or H,C-o° (b) H3C-OH or H;C-NH, (c) or (d) (е) CH3S` CH3SE (f) CH;Se or or Br

(a) Which compound in each of the following pairs will react faster in SN2 reaction with -OH group?(i) CH3Br or CH3I(ii) (CH3)3CCl or CH3Cl

Answer 2

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Answer 3

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Answer 4

Question

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

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Answer 5

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 6

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 7

Chapter 11.3, Problem 5P

Interpretation Introduction

a)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₂N^- or (CH₃)₂NH

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 8

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 9

Interpretation Introduction

b)

Interpretation:

The more reactive nucleophile among the following pairs

(CH₃)₃B or (CH₃)₃N

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 10

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 11

Interpretation Introduction

c)

Interpretation:

The more reactive nucleophile among the following pairs

H₂O or H₂S is to be stated.

Concept introduction:

The major factor which affects the S_N2 reaction is nucleophile. Nucleophile may be negative or neutral charged. The reactivity of a nucleophile varies from reaction to reaction. It depends on the substrate, solvent and reactant concentrations.

Answer 12

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Answer 23

Ch. 11.1 - Prob. 1P Ch. 11.2 - Prob. 2P Ch. 11.2 - Prob. 3P Ch. 11.3 - Prob. 4P Ch. 11.3 - Prob. 5P Ch. 11.3 - Rank the following compounds in order of their...Ch. 11.3 - Organic solvents like benzene, ether, and...Ch. 11.4 - Prob. 8P Ch. 11.4 - Prob. 9P Ch. 11.4 - Prob. 10P

Chapter 11 Solutions